Artículos de revistas
Synthesis of acylsilanes via oxidative hydrolysis of 2-silyl-1,3-dithianes mediated by N-bromosuccinimide
Registro en:
Journal Of Organometallic Chemistry. Elsevier Science Sa, v. 603, n. 2, n. 220, n. 224, 2000.
0022-328X
WOS:000088285800012
10.1016/S0022-328X(00)00181-9
Autor
Patrocinio, AF
Moran, PJS
Institución
Resumen
The oxidative method for the hydrolysis of 1,3-dithianes was applied to 2-silyl-1,3-dithianes using N-bromosuccinimide providing acylsilanes with good yields under a short reaction period. The oxidation of aroylsilanes to carboxylic acid was prevented by the addition of bases and the lowering of the reaction temperature. (C) 2000 Elsevier Science S.A. All rights reserved. 603 2 220 224