Artículos de revistas
Oxidations with acyl nitrates: A simple and rapid method for preparing quinones, ketones and aldehydes
Registro en:
Tetrahedron Letters. Pergamon-elsevier Science Ltd, v. 37, n. 29, n. 5029, n. 5032, 1996.
0040-4039
WOS:A1996UY35500003
10.1016/0040-4039(96)01008-8
Autor
deOliveira, AP
Moreira, BG
Moran, PJS
Rodrigues, JAR
Institución
Resumen
Hydroquinones are oxidized rapidly and quantitatively with acyl nitrates or trimethylsilyl nitrates to quinones. Primary and secondary alcohols are oxidized to aldehydes and ketones in good yields with acyl nitrates suported on montmorillonite or chrysotile. A mechaninsm is proposed based on a nitrate intermediate isolated from the reaction mixture. Copyright (C) 1996 Elsevier Science Ltd 37 29 5029 5032