Artículos de revistas
Assessing the absolute configuration of (7S,8R)-(-)-epoxyjasmone
Registro en:
Journal Of Molecular Catalysis B-enzymatic. Elsevier Science Bv, v. 60, n. 41732, n. 133, n. 137, 2009.
1381-1177
WOS:000269466600006
10.1016/j.molcatb.2009.04.010
Autor
Pinheiro, L
de Oliveira, LG
Marsaioli, AJ
Institución
Resumen
The absolute configuration of cis-epoxyjasmone (-)-2, isolated from Trichosporum cutaneum CCT 1903 whole cells, has been unambiguously established as (7S,8R), [alpha](D)(20)-29.0 degrees (c 1.3, CHCl(3)), by a new two step method, using a regioselective epoxide opening as the key step followed by Mosher acid derivatization. (C) 2009 Elsevier B.V. All rights reserved. 60 41732 133 137