Volumetric properties of binary mixtures of ethers and acetonitrile: Experimental results and application of the Prigogine-Flory-Patterson theory

dc.creatorTorres, RB
dc.creatorOrtolan, MI
dc.creatorVolpe, PLO
dc.date2008
dc.dateMAR
dc.date2014-11-14T00:54:37Z
dc.date2015-11-26T16:03:28Z
dc.date2014-11-14T00:54:37Z
dc.date2015-11-26T16:03:28Z
dc.date.accessioned2018-03-28T22:52:42Z
dc.date.available2018-03-28T22:52:42Z
dc.identifierJournal Of Chemical Thermodynamics. Academic Press Ltd Elsevier Science Ltd, v. 40, n. 3, n. 442, n. 459, 2008.
dc.identifier0021-9614
dc.identifierWOS:000256444100013
dc.identifier10.1016/j.jct.2007.09.007
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/76236
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/76236
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/76236
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1265272
dc.descriptionin this work, densities of binary mixtures of {acetonitrile + di-n-butyl ether (DNBE), or + tetrahydrofuran (THF), or + 1,4-dioxane (DIO), or + di-isopropyl ether (DIPE)}, have been determined under atmospheric pressure as a function of composition and temperature using a vibrating-tube densimeter. The temperatures studied were T = (288.15, 293.15, 298.15, and 303.15) K. The excess molar volumes (V-m(E)), calculated from density data, are negative over the whole mole fraction range for the temperature range studied. The partial molar volumes at infinite dilution of each component ((V) over bar (infinity)(i)) have been determined using three different methods. The experimental results have been used to test the applicability of the Prigogine-Flory-Patterson (PFP) theory. (c) 2007 Elsevier Ltd. All rights reserved.
dc.description40
dc.description3
dc.description442
dc.description459
dc.languageen
dc.publisherAcademic Press Ltd Elsevier Science Ltd
dc.publisherLondon
dc.publisherInglaterra
dc.relationJournal Of Chemical Thermodynamics
dc.relationJ. Chem. Thermodyn.
dc.rightsfechado
dc.rightshttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.sourceWeb of Science
dc.subjectvolumetric properties
dc.subjectacetonitrile
dc.subjecttetrahydrofuran
dc.subject1,4-dioxane
dc.subjectdi-isopropyl ether
dc.subjectdi-n-butyl ether
dc.subjectPFP theory
dc.subjectExcess Molar Volumes
dc.subjectN-butyl Ether
dc.subjectNormal Paraffin Hydrocarbons
dc.subjectVapor-liquid-equilibria
dc.subjectChain Molecule Liquids
dc.subject298.15 K
dc.subjectDifferent Temperatures
dc.subjectAtmospheric-pressure
dc.subjectRefractive-index
dc.subjectEras-model
dc.titleVolumetric properties of binary mixtures of ethers and acetonitrile: Experimental results and application of the Prigogine-Flory-Patterson theory
dc.typeArtículos de revistas


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