Artículos de revistas
Theoretical Evidence For A First-order Liquid-liquid Phase Transition In Gallium.
Registro en:
The Journal Of Chemical Physics. , v. 130, n. 22, p. 221101 - , 2009.
10897690
2-s2.0-69849113435
Autor
Carvajal Jara D.A.
Fontana Michelon M.
Antonelli A.
de Koning M.
Institución
Resumen
We report on theoretical results that lend support to recent experimental observations suggesting the existence of a first-order liquid-liquid phase transformation (LLPT) in gallium. Using molecular dynamics simulation based on a modified embedded-atom model, we observe a transition from a high-density to a low-density liquid in the supercooled regime. The first-order character of the transition is established through the detection of the release of latent heat and our findings suggest that the LLPT terminates in a critical point that is located in the tensile-strained domain of the metastable phase diagram. 130 22 221101