Actas de congresos
Modelling Of A Slurry Bubble Column Reactor Applied To The Hydroconversion Of Heavy Oils
Registro en:
Chemical Engineering Science. Elsevier Science Ltd, Oxford, United Kingdom, v. 52, n. 21-22, p. 4179 - 4185, 1997.
92509
2-s2.0-0031278335
Autor
Carbonell M.M.
Guirardello R.
Institución
Resumen
This work uses a computational fluid dynamics approach for the simulation of a slurry bubble column reactor, applied in the hydroconversion of heavy oils under severe temperature and pressure operating conditions. Simulations are carried out in two steps: first, the fluid dynamics is determined by the calculation of the pressure drop in the bed and the radial distribution of gas and slurry for the holdup, effective viscosity (dispersion) and velocity. Then a thermal cracking reaction is simulated and the oil conversion to lighter fractions such as gasoil, diesel, naphtha and gases is obtained. Results show the recirculation pattern in the reactor which leads to a high degree of backmixing in the slurry phase. Temperature and liquid residence time are found to have a great influence in the oil cracking conversion.This work uses a computational fluid dynamics approach for the simulation of a slurry bubble column reactor, applied in the hydroconversion of heavy oils under severe temperature and pressure operating conditions. Simulations are carried out in two steps: first, the fluid dynamics is determined by the calculation of the pressure drop in the bed and the radial distribution of gas and slurry for the holdup, effective viscosity (dispersion) and velocity. Then a thermal cracking reaction is simulated and the oil conversion to lighter fractions such as gasoil, diesel, naphtha and gases is obtained. Results show the recirculation pattern in the reactor which leads to a high degree of backmixing in the slurry phase. Temperature and liquid residence time are found to have a great influence in the oil cracking conversion. 52 21-22 4179 4185 Abreu, J.C., (1995) Modelagem e Simulação de Reator de Leito Expandido Aplicado ao Hidroprocessamento de Óleos Pesados e Resíduos de Destilação, , M.Sc. dissertation, UNICAMP, Brazil Beanton, W.I., Bertolacini, R.J., Resid Hydroprocessing at Amoco (1991) Catal. Rev. Sci. Engng, 33, pp. 281-317 Carbonell, M.M., (1996) Modelagem e Simulação de Reator Fluidizado Trifásico Aplicado ao Processo de Hidroconversão de Óleos Pesados, , M.Sc. dissertation, UNICAMP, Brazil Chen, Z., Zheng, C., Feng, Y., Hofmann, H., Modelling of three-phase fluidized beds based on local bubble characteristics measurements (1995) Chem. Engng Sci., 50, pp. 231-236 Dudukovic, M.P., Devanathan, N., Bubble column reactors: Some recent developments (1993) Chemical Reactor Technology for Environmentally Safe Reactors and Products, pp. 353-377. , eds. H. I. Lasa, G. Dogu and A. Ravella, Kluwer Academic Publishers, Dordrecht Fan, L.S., (1989) Gas-Liquid-Solid Fluidization Engineering, , Butterworths, London HYSIM® (1994) Hyprotech Ltda. CanadaGasche, H.E., Edinger, C., Kompel, H., Hofmann, H., A fluid dynamically based model of bubble column reactors (1990) Chem. Engng Technol., 13, pp. 341-349 Grienberger, J., Hofmann, H., Investigations and modelling of bubble columns (1992) Chem. Engng Sci., 47, pp. 2215-2220 Menzel, T., Weide, T., Staudacher, O., Wein, O., Onken, U., Reynolds shear stress for modeling of bubble column reactors (1990) Ind. Engng Chem. Res., 29, pp. 988-994 Mosby, J.F., Buttke, R.D., Cox, J.A., Nikolaides, C., Process characterization of expanded-bed reactors in series (1986) Chem. Engng Sci., 41, pp. 989-995 Patankar, S.V., (1980) Numerical Heat Transfer and Fluid Flow, , Hemisphere, Washington, DC Reichardt, H., (1951) Z. Angew. Math. Mech., 31, p. 208 Tarmy, B.L., Chang, M., Coulaloglou, C.A., Ponzi, P.R., The Three Phase Hydrodynamic Characteristics of the EDS Coal Liquefaction Reactors: Their Development and Use in Reactor Scaleup (1984) Institution of Chemical Engineers Symposium Series, Vol. 87, 8th International Symposium on Chemical Reaction Engineering, 87. , Edinburg, 10-13 September Torvik, R., Svendsen, H.F., Modelling of slurry reactors. A fundamental approach (1990) Chem. Engng Sci., 45, pp. 2325-2332 Trambouze, P., Engineering of hydrotreating process (1993) Chemical Reactor Technology for Environmentally Safe Reactors and Products, pp. 409-424. , eds. H. I. Lasa, G. Dogu and A. Ravella, Kluwer Academic Publishers, Dordrecht