Cyclohexane Oxidation Using Transition Metal-containing Aluminophosphates (mapo-vfi)

dc.creatorLuna F.J.
dc.creatorUkawa S.E.
dc.creatorWallau M.
dc.creatorSchuchardt U.
dc.date1997
dc.date2015-06-30T14:49:53Z
dc.date2015-11-26T15:05:11Z
dc.date2015-06-30T14:49:53Z
dc.date2015-11-26T15:05:11Z
dc.date.accessioned2018-03-28T22:15:59Z
dc.date.available2018-03-28T22:15:59Z
dc.identifier
dc.identifierJournal Of Molecular Catalysis A: Chemical. , v. 117, n. 01/03/15, p. 405 - 411, 1997.
dc.identifier13811169
dc.identifier10.1016/S1381-1169(96)00271-3
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-0030928823&partnerID=40&md5=f0154cc0f36bbdacd248203effa4a813
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/100250
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/100250
dc.identifier2-s2.0-0030928823
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1257022
dc.descriptionThe preparation of Co-, Cr-, Fe-, Mn-, Ti-, and V-containing aluminophosphates (MAPO) with VFI structure is described. Physico-chemical techniques were used to characterize the solids synthesized. The MAPO-VFI were compared to AIPO-VFI impregnated with the various metals confirming the isomorphous substitution of Co, Cr, Fe, and Ti into the structure. V is coordinated to defect sites and Mn probably precipitated as oxide on the crystal surface. V- and CrAPO-VFI are active catalysts for the oxidation of cyclohexane with tert-butyl hydroperoxide producing cyclohexanone with some cyclohexanol and cyclohexene. CrAPO-VFI was recycled twice without significant loss of activity. On the other hand, VAPO VFI showed significant metal leaching.
dc.description117
dc.description01/03/15
dc.description405
dc.description411
dc.descriptionDavis, M.E., Saldarriaga, C., Montes, C., Garces, J., Crowder, C., (1988) Nature, 331, p. 698
dc.descriptionDavis, M.E., Montes, C., Hathaway, P.E., Garces, J.M., (1989) Stud. Surf. Sci. Catal., 49, p. 199
dc.descriptionKraushaar-Czarnetzki, B., Dogterom, R.J., Stork, W.H.J., Emeis, K.A., Van Braam Houckgeest, J.P., (1993) J. Catal., 141, p. 140
dc.descriptionPrasad, S., Yang, T.-C., (1994) Catal. Lett., 28, p. 269
dc.descriptionShinde, R.F., Balakrishnan, I., (1991) J. Phys. D: Appl. Phys., 24, p. 1486
dc.descriptionSingh, P.S., Shaikh, R.A., Bandyopadhyay, R., Rao, B.S., (1995) J. Chem. Soc., Chem. Commun., p. 2255
dc.descriptionIssakov, J., Litvin, E., Minachev, Ch., Öhlmann, G., Scharf, V., Thome, R., Tißler, A., Unger, B., (1994) Stud. Surf. Sci. Catal., 84, p. 2005
dc.descriptionStöcker, M., Akporiaye, D., Lillerud, K.-P., (1991) Appl. Catal. Lett., 69, pp. L7
dc.descriptionSchmidt, W., Schüth, F., Reichert, H., Unger, K., Zibrowius, B., (1992) Zeolites, 12, p. 2
dc.descriptionArends, I.W.C.E., Sheldon, R.A., Wallau, M., Schuchardt, U., Angew. Chem., , submitted
dc.descriptionVanoppen, D.L., De Vos, D.E., Genet, M.J., Rouxhet, P.G., Jacobs, P.A., (1995) Angew. Chem. Int. Ed. Engl., 34, p. 560
dc.descriptionRigutto, M.S., Van Bekkum, H., (1993) J. Mol. Catal., 81, p. 77
dc.descriptionBlasco, T., Concepción, P., López Nieto, J.M., Pérez-Pariente, J., (1995) J. Catal., 152, p. 1
dc.descriptionChen, J.D., Sheldon, R.A., (1995) J. Catal., 153, p. 1
dc.descriptionUlagappan, N., Krishnasamy, V., (1995) J. Chem. Soc., Chem. Commun., p. 373
dc.languageen
dc.publisher
dc.relationJournal of Molecular Catalysis A: Chemical
dc.rightsfechado
dc.sourceScopus
dc.titleCyclohexane Oxidation Using Transition Metal-containing Aluminophosphates (mapo-vfi)
dc.typeActas de congresos


Este ítem pertenece a la siguiente institución