Artículos de revistas
Thermodynamics Of The Nickel, Cobalt And Zinc Removal From Ethanolic Solution By P-aminobenzoic Acid Intercalated On Layered Calcium Phosphate
Registro en:
Thermochimica Acta. Elsevier, v. 589, n. , p. 107 - 113, 2014.
406031
10.1016/j.tca.2014.05.017
2-s2.0-84902173696
Autor
De Souza F.M.
Dias A.P.B.
Babeto B.
Pelisson S.
Lazarin A.M.
Sernaglia R.L.
Andreotti E.I.S.
Airoldi C.
Institución
Resumen
Crystalline lamellar calcium phosphate retained p-aminobenzoic acid inside its cavity without leaching. The adsorption isotherms from ethanol gave the maximum adsorption capacities of 6.44, 3.34 and 1.62 mmol g-1 for nickel, cobalt and zinc, respectively. The energetic effects caused by metallic cation interactions were determined through calorimetric titration at the solid/liquid interface and gave a net thermal effect that enabled enthalpy and equilibrium constant calculations. Complete thermodynamic data composed of exothermic enthalpy, negative free Gibbs energy and positive entropy conformed to a set of favorable cation/basic center interactions, to indicate that these materials could be useful tools to eliminate undesirable cations from ethanolic systems. © 2014 Elsevier B.V. 589
107 113 Ogawa, M., 6 Organized molecular assemblies on the surfaces of inorganic solids - photofunctional inorganic-organic supramolecular systems (1998) Annual Reports on the Progress of Chemistry - Section C, 94, pp. 209-257 Alberti, G., Bein, T., (1996) Comprehensive Supramolecular Chemistry, 7 VOL.. , Pergamon Press New York Clearfield, A., (1982) Inorganic Ion Exchange Material, , CRC Press Inc. Boca Raton Jacobson, A.J., Intercalation reaction of layered compounds (1992) Solid State Chemistry Compounds, , A.K. Cheetham, P. Day, Clarendon Press Oxford Lerf, A., Intercalation compounds in layered host lattices: Supramolecular chemistry in nanodimension (2000) Handbook of Nanostructured Materials and Nanotechnology, 5 VOL.. , H.S. Nalwa, Academic Press New York Ogawa, M., Kuroda, K., Photofunctions of intercalation compounds (1995) Chem. Rev., 95, pp. 399-438 Clearfield, A., Metal-Phosphonate Chemistry (1998) Progress In Inorganic Chemistry, 47, pp. 371-510 Cabeza, A., Aranda, M.A.G., Martinez-Lara, M., Bruque, S., Sanz, J., Ab Initio Powder Structure Determination and Thermal Behavior of a New Lead(II) Phenylphosphonate, Pb(O3PC6H5) (1996) Acta Crystallographica Section B: Structural Science, 52 (6), pp. 982-988 Da Silva, O.G., Da Fonseca, M.G., Arakaki, L.N.H., Silylated calcium phosphates and their new behavior for copper retention from aqueous solution (2007) Colloids and Surfaces A: Physicochemical and Engineering Aspects, 301 (1-3), pp. 376-381. , DOI 10.1016/j.colsurfa.2006.12.072, PII S0927775707000088 Poojary, D.M., Grohol, D., Clearfield, A., Synthesis and X-ray powder structure of a novel porous uranyl phenylphosphonate containing unidimensional channels flanked by hydrophobic regions (1995) Angew. Chem. Int. Ed., 34, pp. 1508-1510 Sales, J.A.A., Airoldi, C., Calorimetric investigation of metal ion adsorption on 3- glycidoxypropyltrimethylsiloxane + propane-1,3-diamine immobilized on silica gel (2005) Thermochimica Acta, 427 (1-2), pp. 77-83. , DOI 10.1016/j.tca.2004.08.015 Ruiz, V.S.O., Airoldi, C., Thermochemical data for n-alkylmonoamine intercalation into crystalline lamellar zirconium phenylphosphonate (2004) Thermochim. Acta, 420, pp. 73-78 Airoldi, C., Roca, S., Calorimetric study of intercalation of n-alkyldiamines into α-titanium hydrogenphosphate (1996) Journal of Materials Chemistry, 6 (12), pp. 1963-1966 Ruiz, V.S.O., Petrucelli, G.C., Airoldi, C., Inorganic-organic hybrids derived from lamellar acidic kenyaite immobilizations for cation removal at the solid/liquid interface (2006) Journal of Materials Chemistry, 16 (24), pp. 2338-2346. , DOI 10.1039/b515676a Vaghetti, J.C.P., Lima, E.C., Royer, B., Brasil, J.L., Cunha, B.M., Simon, N.M., Cardoso, N.F., Noreña, C.P.Z., Application of Brazilian-pine fruit coat as a biosorbent to removal of Cr(VI) from aqueous solution - Kinetics and equilibrium study (2008) Biochem. Eng. J., 42, pp. 67-76 Karadag, D., Koc, Y., Turan, M., Ozturk, M., A comparative study of linear and non-linear regression analysis for ammonium exchange by clinoptilolite zeolite (2007) Journal of Hazardous Materials, 144 (1-2), pp. 432-437. , DOI 10.1016/j.jhazmat.2006.10.055, PII S0304389406012799 Lazarin, A.M., Airoldi, C., Layered crystalline barium phosphate organofunctionalized for cation removal (2006) Chemistry of Materials, 18 (9), pp. 2226-2232. , DOI 10.1021/cm0519333 Guerra, D.L., Airoldi, C., Sousa, K.S., Adsorption and thermodynamic studies of Cu(II) and Zn(II) on organofuncionalized-kaolinitre (2008) Appl. Surf. Sci., 254, pp. 5157-5163 Monteiro Jr., O.A.C., Airoldi, C., The influence of chitosans with defined degrees of acetylation on the thermodynamic data for copper coordination (2005) Journal of Colloid and Interface Science, 282 (1), pp. 32-37. , DOI 10.1016/j.jcis.2004.08.165, PII S0021979704008689 Petrucelli, G.C., Meirinho, M.A., Macedo, T.R., Airoldi, C., Crystalline polysilicate magadiite with intercalated n-alkylmonoamine and some correlations involving thermochemical data (2006) Thermochimica Acta, 450 (1-2), pp. 16-21. , DOI 10.1016/j.tca.2006.06.023, PII S0040603106003649 Airoldi, C., Oliveira, S.F., On the thermochemistry of intercalation of N-alkylamines into alpha-titanium hydrogen-phosphate (1991) Struct. Chem., 2, pp. 41-46 Yang, X.-B., Fu, X.-K., Zeng, R.-Q., Intercalation of non-aromatic heterocyclic amines into layered zirconium glycine-N,N-dimethylphosphonate (2010) Chem. Pap., 64, pp. 118-122 Kim, H.-N., Keller, S.W., Mallouk, T.E., Schmitt, J., Decher, G., Characterization of Zirconium Phosphate/Polycation Thin Films Grown by Sequential Adsorption Reactions (1997) Chemistry of Materials, 9 (6), pp. 1414-1421 Airoldi, C., Lima, C.B.A., Topotactic exchange and intercalation of calcium phosphate (2004) Solid State Sci., 6, pp. 1245-1250 Capkova, P., Schenk, H., Host-guest complementarity and crystal packing of intercalated layered structures (2003) Journal of Inclusion Phenomena, 47 (1-2), pp. 1-10. , DOI 10.1023/B:JIPH.0000003826.01697.42 Yang, X.-B., Fu, X.-K., Zeng, R.-Q., Intercalation of basic amino acids into layered zirconium proline-N-methylphosphonate phosphate (2011) Chem. Pap., 65, pp. 676-681 Nunes, L.M., Airoldi, C., Thermochemical data on intercalation of aromatic amines into crystalline α-titanium hydrogenphosphate (2005) Thermochimica Acta, 435 (1), pp. 118-123. , DOI 10.1016/j.tca.2004.06.019, PII S0040603104003107 Pessoa, C.A., Gushikem, Y., Kubota, L.T., Electrochemical Study of Methylene Blue Immobilized in Zirconium Phosphate (1997) Electroanalysis, 9 (10), pp. 800-803 Murakami, Y., Imai, H., Synthesis and thermal changes of calcium phenylphosphate and calcium phenylphosphonate (1992) J. Ceram. Soc. Jpn., 100, pp. 439-443 Nadhu, N., Radhakrishnan, P.K., Grunent, M., Weinbergr, P., Linet, W., A thermal decomposition study on cobalt(II) complexes of 1,2-di(imino-4′-antipyrinyl)ethane (2003) Thermochim. Acta, 400, pp. 29-36 Prado, A.G.S., Airoldi, C., Adsorption, preconcentration and separation of cations on silica gel chemically modified with the herbicide 2,4-dichlorophenoxyacetic acid (2001) Analytica Chimica Acta, 432 (2), pp. 201-211. , DOI 10.1016/S0003-2670(00)01372-6, PII S0003267000013726 Fonseca, M.G., Airoldi, C., Phyllosilicate-like structure anchored silylating agents: Calorimetric data on divalent cation-aminated centre interactions in the lamellar cavity (1999) J. Chem. Soc., Dalton Trans., 42, pp. 3687-3692 Lazarin, A.M., Airoldi, C., Layered crystalline barium phosphate organofunctionalized for cation removal (2006) Chemistry of Materials, 18 (9), pp. 2226-2232. , DOI 10.1021/cm0519333 De Magalhaes Padilha, P., Rocha, J.C., Moreira, J.C., De Sousa Campos, J.T., Do Carmo Federici, C., Preconcentration of heavy metals ions from aqueous solutions by means of cellulose phosphate: An application in water analysis (1997) Talanta, 45 (2), pp. 317-323. , DOI 10.1016/S0039-9140(97)00134-3, PII S0039914097001343 Al-Asheh, S., Duvnjak, Z., Sorption of heavy metals by canola meal (1999) Water, Air, and Soil Pollution, 114 (3-4), pp. 251-276. , DOI 10.1023/A:1005093821620 Fonseca, M.G., Airoldi, C., Mercaptopropyl magnesium phyllosilicate-thermodynamic data on the interaction with divalent cations in aqueous solution (2000) Thermochim. Acta, 359, pp. 1-9 Marcus, Y., (1985) Ion Salvation, , Wiley London Bem-Naim, A., (1987) Solvation Thermodynamics, , Plenum Press New York