Artículos de revistas
Synthesis Of Manganese Porphyrinosilica Imprinted With Templates Using The Sol-gel Process
Registro en:
Journal Of Non-crystalline Solids. , v. 273, n. 01/03/15, p. 150 - 158, 2000.
223093
2-s2.0-0000244153
Autor
Sacco H.C.
Ciuffi K.J.
Biazzotto J.C.
Zuccki M.R.
Leite C.A.P.
Nascimento O.R.
Serra O.A.
Iamamoto Y.
Institución
Resumen
The optimized conditions for the preparation of a new manganese porphyrinosilica-template material are reported. The manganese porphyrinosilica-template was prepared by the sol-gel process, by the reaction of -SO2Cl groups present in the phenyl rings of MnTDC(SO2Cl)PPCl with 3-aminopropyltriethoxysilane. The reaction produces a precursor porphyrinopropylsilyl species, which were then polymerized with tetraethoxysilane. The presence of manganese porphyrin on xerogel is confirmed by ultraviolet visible absorption spectroscopy and thermogravimetric analysis (TGA). The prepared materials have surface areas between 19 and 674 m2 g-1. Electron spectroscopy imaging of the materials show that manganese distribution in the xerogel is uniform. Both manganese(III) porphyrinosilica-template and a similar iron(III) porphyrinosilica-template can catalyze the epoxidation of cyclooctene using iodozylbenzene as oxygen donor. The metalloporphyrinosilica-template presents catalytic activity similar to that of metaloporphyrin in solution. © 2000 Elsevier Science B.V. All rights reserved. 273 01/03/15 150 158 Brinker, C.J., Scherer, G.W., (1990) The Physics and Chemistry of Sol-gel Processing, , Academic Press, San Diego, California Lan, E.H., Dave, B.C., Fukuto, J.M., Dunn, B., Zink, J.I., Valentine, J.S., (1999) J. Mater. Chem., 9, p. 45 Gill, I., Ballesteros, A., (1998) J. Am. Chem. Soc., 120, p. 8587 Zhou, H.S., Honma, I., (1998) Chem. Lett., p. 973 Das, T.K., Khan, I., Rousseau, D.L., Friedman, J.M., (1998) J. Am. Chem. Soc., 120, p. 10268 Dave, B.C., Dunn, B., Valentine, J.S., Zink, J.I., (1994) Anal. Chem., 66, p. 1120 Martinez-Lorente, M.A., Battioni, P., Kleemiss, W., Bartoli, J.F., Mansuy, D., (1996) J. Molec. Catal. A, 113, p. 343 Dolphin, D., Traylor, T.G., Xie, L.Y., (1997) Acc. Chem. Res., 30, p. 251 Meunier, B., (1992) Chem. Rev., 92, p. 1411 Iamamoto, Y., Ciuffi, K.J., Sacco, H.C., Prado, C.M.C., Nascimento, O.R., (1994) J. Molec. Catal., 88, p. 167 Iamamoto, Y., Ciuffi, K.J., Sacco, H.C., Iwamoto, L.S., Nascimento, O.R., Prado, C.M.C., (1997) J. Molec. Catal., 116, p. 405 Battioni, P., Cardin, E., Louloudi, M., Schollhorn, G., Spyroullias, G.A., Mansuy, D., Traylor, T.G., (1996) Chem. Commun., p. 2037 Ciuffi, K.J., Sacco, H.C., Valim, J.B., Manso, C.M.C.P., Serra, O.A., Nascimento, O.R., Vidoto, E.A., Iamamoto, Y., (1999) J. Non-Cryst. Solids, 247, p. 146 Mark, J.E., Lee, C.Y.-C., Bianconi, P.A., (1995) Hybrid Organic-Inorganic Composites, , American Chemical Society, Washington, DC Bystrom, S.E., Borje, A., Akermark, B., (1993) J. Am. Chem. Soc., 115, p. 2081 Makote, R., Collinson, M.M., (1998) Chem. Mater., 10, p. 2440 Lindsey, J.S., Schreiman, I.C., Hsu, H.C., Kearney, P.C., Marguerettaz, A.M., (1987) J. Org. Chem., 52, p. 827 Rocha Gonsalves, A.M.A., Johnstone, R.A.W., Pereira, M.M., Santana, A.M.P., Serra, A.C., Sobral, A.J.F.N., Stocks, P.A., (1996) Heterocyles, 4, p. 43 Adler, A.D., Longo, F.R., Kampas, F., Kim, J., (1970) J. Inorg. Nucl. Chem., 32, p. 2443 Morrison, R., Boyd, R., (1983) Quimica Orgânica, , Fundação Calouste Gulbenkian, Lisbon Sharefkin, J.G., Saltzmann, H., (1963) Org. Synth., 43, p. 62 Cardoso, A.H., Leite, C.A.P., Galembeck, F., (1998) Langmuir, 14, p. 3189 Reimer, L., Zepke, U., Moesch, J., Schulze-Hillert, St., Messemer, M., Probst, W., Weimer, E., (1992) EELS Spectroscopy: A Reference Handbook of Standard Data for Identification and Interpretation of Electron Energy Loss Spectra and for Generation of Electron Spectroscopic Images, , Carl Zeiss, Oberkochen, Germany Brunauer, S., Emmet, P.H., Teller, E., (1938) J. Am. Chem. Soc., 60, p. 309 Sacco, H.C., (1999), PhD thesis, Universidade Estadual Paulista Júlio de Mesquita Filho, Institute de QuímicaCooke, P.R., Lindsay Smith, J.R., (1992) Tetrah. Lett., 33, p. 2737 Fleischer, E.B., Fine, D.A., (1978) Inorg. Chim. Acta, 29, p. 267 Pouchert, C.J., (1981) The Aldrich Library of Infrared Spectra, , Aldrich Chemical Company Dhas, N.A., Raj, P., Gedanken, A., (1998) Chem. Mater., 10, p. 3278 Sako, S., Kimura, K., (1985) Surf. Sci., 156, p. 511 Groves, J.T., Stern, M.K., (1988) J. Am. Chem. Soc., 110, p. 8628 Rodgers, K.R., Goff, H.M., (1988) J. Am. Chem. Soc., 110, p. 7049 Smegal, J.A., Hill, C.L., (1983) J. Am. Chem. Soc., 105, p. 3515 Lippard, S.J., Berg, J.M., (1994) Principles of Bioinorganic Chemistry, , University Science Books, Mill Valley, California Williams, D.H., Fleming, J., (1989) Spectroscopy Methods in Organic Chemistry, 4th Ed., , Mc Graw-Hill, New York Lindsay Smith, J.R., Sheldon, R.A., (1994) Metalloporphyrins in Catalytic Oxidations, , Marcel Dekker, New York, Chapter 11 Gilmartin, C., Lindsay Smith, J.R., (1995) J. Chem. Soc. Perkin Trans., 2, p. 243 Cooke, P.R., Gilmartin, C., Gray, G.W., Lindsay Smith, J.R., (1995) J. Chem. Soc. Perkin Trans., 2, p. 1573 Thellend, A., Battioni, P., Mansuy, D., (1994) J. Chem. Soc., Chem. Commun., p. 1035