Artículos de revistas
A Multitubular Reactor For Obtention Of Acetaldehyde By Oxidation Of Ethyl Alcohol
Registro en:
Chemical Engineering Science. , v. 47, n. 9-11, p. 2571 - 2576, 1992.
92509
10.1016/0009-2509(92)87095-8
2-s2.0-0026788692
Autor
Filho R.M.
Domingues A.
Institución
Resumen
In this work an alternative process for the obtention of acetaldehyde is presented. It is based on the oxidation of ethyl alcohol over commercial Fe-Mo catalyst. Experimental kinetic data, obtained in an integral reactor, were interpreted by a Temkin's type mechanism, although it is possible to treat the data by a known mechanism similar to the oxidation of methanol to formaldehyde. A new multitubular reactor is then proposed with the obtained rate equation. It is baffled but windowless, so that better temperature control is achieved when compared with conventional reactors. The process considered here exhibits better performance than the best known processes in terms of higher conversions, stability and yield in acetaldehyde. © 1992. 47 9-11 2571 2576 Day, Oxidation of ethyl-alcohol (1931) Journal of Physical Chemistry, 35, pp. 9272-9279 Dente, Poppi, Pasquon, Cinetica dell'ossidazione del metanolo a formaldeide con catalizzatore a base di ossidi di Fe e Mo (1964) La Chimica e I'Industria, 46 (11), pp. 1326-1336 Domingues, Modelagem do Processo de Oxidação do Etanol a Acetaldeído (1992) Tese de Mestrado, UNICAMP, FEQ/DPQ/LOPCA, , Campinas, São Paulo, Brasil, in preparation Froment, Bischoff, (1990) Chemical Reactor Analysis and Design, , 2nd edition, John Wiley & Sons Maciel Filho, Oxidação Catalítica de Etanol a Acetaldeído sobre Catalisador de Ferro Molibdênio (1985) Tese de Mestrado 069/85, , UNICAMP, FEC/DEQ, Campinas, Sao Paulo, Brasil Maciel Filho, Modelling and Control of Multitubular Reactors (1989) PhD Thesis, , Department of Chemical Engineering, The University of Leeds, Leeds England, UK Maciel Filho, Domingues, Modelagem Detalhada de Reator de Leito Fixo para conversão de Etanol a Acetaldeído (1991) XIX ENEMP - Encontro Nacional Sobre escoamento em Meios porosos, , UNICAMP, Campinas, São Paulo, Brasil McGreavy, Maciel Filho, Insights on Temperature sensor Location in Multitubular Reactors (1989) Computer Integrated Process Engineering, , Institution of Chemical Engineers, Leeds, England McGreavy, Maciel Filho, Dynamic Behaviour of Fixed Bed Catalytic Reactors (1989) IFAC-Symposium on Dynamics and Control of Chemical Reactors, Distillation Columns and batch Processes, , The Netherlands Moura, Oxidação do Etanol a Acetaldeído sobre Catalisador de Cobre Oxidado (1984) Tese de Duotorado 04/84, , UNICAMP, FEC/DEM, Campinas, São Paulo, Brasil