Artículos de revistas
Intrazeolite Metal Carbonyl Kinetics: 12co Substitution In Mo(12co)6-na56y By Pme3 And 13co
Registro en:
Journal Of The Chemical Society, Chemical Communications. , v. , n. 3, p. 141 - 143, 1991.
224936
10.1039/C39910000141
2-s2.0-37049078661
Autor
Ozin G.A.
Ozkar S.
Pastore H.O.
Poe A.J.
Vichi E.J.S.
Institución
Resumen
The first kinetic study is reported for archetypical substitution reactions of PMe3 and 13CO with the well defined intrazeolite system, Mo(12CO)6-Na56Y, for which excellent isosbestic points and first order behaviour are obtained, the activation parameters indicate a highly ordered 'supramolecular' transition state consisting of activated Mo(12CO)6 and PMe3 or 13CO all anchored to the Na+ ions in the α-cage of the host lattice.
3 141 143