Artículos de revistas
Looking At Hydrogen Motions In Confinement: The Uniqueness Of Quasi-elastic Neutron Scattering
Registro en:
European Physical Journal: Special Topics. Springer Verlag, v. 223, n. 9, p. 1831 - 1847, 2014.
19516355
10.1140/epjst/e2014-02229-4
2-s2.0-84908423815
Autor
Fischer J.
Tsapatsaris N.
de Paula E.
Bordallo H.N.
Institución
Resumen
Why in a barren and hot desert, clays can contain a significant fraction of water? Why does concrete crack? How can we demonstrate that complexation of a drug does not alter its conformation in a way that affects its functionality? In this paper we present results on various studies using Quasi-Elastic Neutron Scattering aimed at clarifying these questions. To allow for a better understanding of neutron scattering, a brief introduction to the basics of its theory is presented. Following the theoretical part, experimental results dealing with the effects of confinement on the water dynamics caused by the interfaces in clays and the nano- and micro-pores of concrete are reviewed in detail. At the end, recent Quasi-Elastic Neutron Scattering investigations on the complexation of the local anesthetics Bupivacaine (BVC.HCl, C18H28N20.HCl.H2O) and Ropivacaine (RVC.HCl, C17H26N20.HCl.H2O) into the cyclic β-cyclodextrin oligosaccharide are presented. To conclude, the perspectives that the European Spallation Source brings to this subject are discussed. 223 9 1831 1847 Bacon, G.E., (1977) Neutron Scattering in Chemistry, , Butterworths, London: Sears, V.F., (1992) Neutron News, 3, p. 26 Lovesey, S.W., (1984) Theory of Neutron Scattering from Condensed Matter, , Claredon Press, Oxford: Schuster, P., Zundel, G., C. Sandorfy (1976) The Hydrogen Bond, III. , North-Holland Publishing Company, Amsterdam: Bee, M., (1992) Physica B, 182, p. S323 Lechner, R.E., Melzer, R., Fitter, J., (1996) Physica B, 226, p. S86 Rols, S., Herve, J., Schober, H., (2007) C. R. Phys., 8, p. S777 Brubach, J.-B., Mermet, A., Filabozzi, A., Gerschel, A., Lairez, D., Krafft, M.P., Roy, P., (2001) J. Phys. Chem., 105, p. 430 Kyakuno, H., Matsuda, K., Yahiro, H., Inami, Y., Fukuoka, T., Miyata, Y., Yanagi, K., Iijima, S., (2011) J. Chem. Phys., 134, p. 244501 Jacobsen, J., Rodrigues, M.S., Telling, M.T.F., Beraldo, A.L., Santos, S.F., Aldridge, L.P., Bordallo, H.N., (2013) Sci. Rep., 3, p. 2667 Singwi, K.S., Sjolander, A., (1960) Phys. Rev., 119, p. 863 Teixeira, J., Bellissent-Funel, M.-C., Chen, S.H., Dianoux, A.J., (1985) Phys. Rev. A, 31, p. 1913 Bordallo, H.N., Aldridge, L.P., Fouquet, P., Pardo, L.C., Unruh, T., Wuttke, J., Yokaichiya, F., (2009) ACS Appl. Mater. Interf., 1, p. 2154 Sears, V.F., (1966) Can. J. Phys., 44, p. 1299 Bellissent-Funel, M.-C., Chen, S., Zanotti, J.-M., (1995) Phys. Rev. E, 51, p. 4558 Chudley, T., Elliot, R.J., (1966) Proc. Phys. Soc. London, 77, p. 353 Chen, S.-H., Gallo, P., Sciortino, F., Tartaglia, P., (1997) Phys. Rev. E, 56, p. 4231 Frick, H. Buttner, R. Zorn (eds.), Proceedings of the International Workshop on Dynamics in Confinement, J. Phys (2000) IV 10 (PR7) Frick, M. Koza, R. Zorn (eds.), Proceedings of the second International Workshop on Dynamics in Confinement, Eur. Phys. J (2003) E 12(1) Koza, B. Frick, R. Zorn (eds.), Proceedings of the 3rd International Workshop on Dynamics in Confinement, Eur. Phys. J (2007) Special Topics 141(4) Blochowicz, T., Gouirand, E., Fricke, A., Spehr, T., Stuhn, B., Frick, B., (2009) Chem. Phys. Lett., 475, p. 171 http://csiprogress2012.org/, The cement sustainability initiative: Progress report, World Business Council for Sustainable Development, 2002. [Online]Mehta, P.K., Manmohan, D., (2006) ACI Concr. Int., 28, p. 37 Powers, C., Brownyard, T.L., (1948) Studies of the physical properties of hardened Portland cement paste, , Portland Cement Association, Chicago: Neville, A.M., (1996) Properties of Concrete Fourth and Final Edition (John Wiley &, , Sons, New York: Bordallo, H.N., Aldridge, L.P., Desmedt, A., (2006) J. Phys. Chem. B, 110, p. 17966 Bordallo, H.N., Herwig, K.W., Luther, B.M., Levinger, N.E., (2004) J. Chem. Phys., 121, p. 12457 Brunauer, S., Odler, I., Yudenfreund, M., (1970) Highway Res. Rec., 89, p. 328 Fratini, E., Faraone, A., Ridi, F., Chen, S.-H., Baglioni, P., (2013) J. Phys. Chem. C, 117, p. 7358 Damme, H.V., Gmira, A., (2006) Cement Hydrates, in Handbook of Clay Science., edited by B.K. Theng, F. Bergaya, G. Lagaly, , Elsevier, Amsterdam: Swenson, J., Bergman, R., Howells, W.S., (2000) J. Chem. Phys., 113, p. 2873 North, F.K., (1990) Petroleum Geology, , Unwin-Hyman, Boston: Williams, L.B., Canfield, B., Voglesonger, K.M., John, R., (2005) Geology, 33, p. 913 Low, P.F., (1961) Physical chemistry of clay-water interaction, in Advances in Agronomy, No. 13, edited by A.G. Norman, , Academic Press, New York: Bordallo, H.N., Aldridge, L.P., Jock Churchman, G., Gates, W.P., Telling, M.T.F., Kiefer, K., Fouquet, P., Kimber, S.A.J., (2008) J. Phys. Chem. C, 112, p. 19982 Malikova, N., Dubois, E., Turq, P., (2006) J. Phys. Chem. B, 110, p. 3206 Bourg, I.C., Sposito, G., Bourg, G.A.C.M., (2006) Clays and Clay Miner., 54, p. 363 Gates, W.P., Bordallo, H.N., Aldridge, L.P., Seydell, T., Jacobsen, H., Marry, V., Jock Churchman, G., (2012) J. Phys. Chem. C, 116, p. 5558 Bujdak, J., Slosiarikova, H., (1994) J. Thermal Anal. Calorim., 41, p. 825 Snoeck, M., (2012) Local, Reg. Anesthesia, 5, p. 23 de Paula, E., Cereda, C.M.S., Fraceto, L.F., de Araujo, D.R., Franz-Montan, M., Tofoli, G.R., Ranali, J., Groppo, F.C., (2012) Expert Opin. Drug Deliv., 9, p. 1505 Loftsson, T., Duchen, D., (2007) Int. J. Pharm., 329, p. 1 Katageri, R.A., Sheikh, M.A., (2012) Int. Res. J. Pharm., 3, p. 52 Moraes, C.M., Abrami, P., de Paula, E., Braga, A.F.A., Fraceto, L.F., (2007) Int. J. Pharm., 331, p. 99 Partanen, R., Ahro, M., Kallio, M.H.H., Forssell, P., (2002) Eur. Food Res. Technol., 214, p. 242 Pinto, L.M.A., Fraceto, L.F., Santana, M.H.A., Pertinhez, T.A., Oyama Junior, S., de Paula, E., (2005) J. Pharm. Biomed. Anal., 39, p. 956 de Lima, R.A.F., de Jesus, M.B., Cereda, C.M.S., Tofoli, G.R., Cabeça, L.F., Mazzaro, I., Fraceto, L.F., de Paula, E., (2012) J. Drug Target., 20, p. 85 Pinto, L.M.A., de Jesus, M.B., de Paula E, E., Lino, A.C.S., Alderete, J.B., Duarte, H.A., Takahata, Y., (2004) J. Molec. Struc. (Theochem), 678, p. 63 Cabeça, L.F., Figueiredo, I.M., de Paulab, E., Marsaiolia, A.J., (2011) Magn. Reson. Chem., 49, p. 295 Thomas, J.J., Jennings, H.M., Allen, A.J., (2010) J. Phys. Chem. C, 114, p. 7594 Benetti, A., Jacobsen, J., Telling, M.T.F., Garcia-Sakai, V., H.N. Bordallo (2013) ISIS Neutron and Muon Source Annual Review, 2013. , RAL Library, Didcot: