Artículos de revistas
Estimation Of Standard Enthalpies Of Formation Of Crystalline Inorganic And Organometallic Complexes
Registro en:
Journal Of Organometallic Chemistry. , v. 335, n. 1, p. 71 - 83, 1987.
0022328X
10.1016/0022-328X(87)85174-4
2-s2.0-0006471038
Autor
Dias A.R.
Martinho Simoes J.A.
Teixeira C.
Airoldi C.
Chagas A.P.
Institución
Resumen
Good linear correlations have been found between standard enthalpies of formation of crystalline inorganic and organometallic complexes MXnLm and enthalpies of formation of ligands L or LH in their standard reference state. These correlations may be used to estimate enthalpies of formation of new complexes. © 1987. 335 1 71 83 Cox, Pilcher, (1970) Thermochemistry of Organic and Organometallic Compounds, , Academic Press, London and New York Benson, (1976) Thermochemical Kinetics, , Wiley, New York Pedley, Naylor, Kirby, (1986) Thermochemical Data of Organic Compounds, , 2nd, Chapman and Hall, London and New York Sanderson, (1976) Chemical Bonds and Bond Energy, , 2nd, Academic Press, New York Sanderson, (1983) Polar Covalence, , Academic Press, New York Sanderson, (1975) J. Am. Chem. Soc., 97, p. 1367 Sanderson, (1982) J. Org. Chem., 47, p. 3835 Dewar, Storch, (1985) J. Am. Chem. Soc., 107, p. 3898. , See, for example Dewar, Zoebisch, Healy, Stewart, (1985) J. Am. Chem. Soc., 107, p. 3902 Dewar, (1985) J. Phys. Chem., 89, p. 2145 Reid, Prausnitz, Sherwood, (1977) The Properties of Gases and Liquids, , See, for example, 3rd edit., McGraw-Hill, New York No reliable methods for estimating accurate values of enthalpies of sublimation are presently available. See also ref. 1Hisham, Benson, (1985) J. Phys. Chem., 89, p. 1905 Hisham, Benson, (1985) J. Phys. Chem., 89, p. 3417 Hisham, Benson, (1986) J. Phys. Chem., 90, p. 885 Bratsch, Lagowski, (1985) J. Phys. Chem., 89, p. 3310. , and refs. cited therein Sanderson, (1983) J. Am. Chem. Soc., 105, p. 2259. , See refs. 4a, 4b and: Sanderson, (1986) Inorg. Chem., 25, p. 1856 Sanderson, (1986) Inorg. Chem., 25, p. 3518 Pilcher, Skinner, (1982) The Chemistry of the Metal-Carbon Bond, , F.R. Hartley, S. Patai, John Wiley, New York, chapter 2 Smith, (1974) J. Organomet. Chem., 76, p. 171 Dewar, Grady, Stewart, (1984) J. Am. Chem. Soc., 106, p. 6771 Dewar, Friedheim, Grady, (1985) Organometallics, 4, p. 1784 Dewar, Grady, Merz, Jr., Stewart, (1985) Organometallics, 4, p. 1964 Dewar, Holloway, Grady, Stewart, (1985) Organometallics, 4, p. 1973 Dewar, Friedhelm, Grady, Healy, Stewart, (1986) Organometallics, 5, p. 375 Dewar, Merz, Jr., (1986) Organometallics, 5, p. 1494 (a) J.A. Martinho Simões and J.L. Beauchamp, Chem. Rev., to be publishedCalhorda, de C.T. Carrondo, Dias, Domingos, Martinho Simões, Teicxeira, (1986) Organometallics, 5, p. 660 Calhorda, Dias, Galvão, Martinho Simões, (1986) J. Organometal. Chem., 307, p. 167 Calhorda, Dias, Minas da Piedade, Salema, Martinho Simões, (1987) Organometallics, 6, p. 734 Pedley, Rylance, Sussex-N.P.L. Computer Analysed Thermochemical Data: (1977) Organic and Organometallic Compounds, , University of Sussex, Brighton Dias, Dias, Diogo, Galvão, Minas da Piedade, Martinho Simões, (1987) Organometallics, 6, p. 1427 The only value not reported in refs. 12b, 12d and 14 is: ΔH0 f[TiCp2(SC2H5)2,c] = −211.3±8.2 kJ mol−1. (A.R. Dias, J.A. Martinho Simões, and C. Teixeira, to be published)For L = CO ΔH0 f(LH,rs) is replaced by ΔH0 f(L,rs)The only values not reported in refs. 12b, 12d and 14 are: ΔH0 f[WCp2(SC2H5)2,c] = 62.7±5.3 kJ mol−1 and ΔH0 f[WCp2(SC6H5)2,c] = 319.95±5.5 kJ mol−1. (A.R. Dias, J.A. Martinho Simões, and C. Teixeira, to be published)Data for the standard enthalpies of formation of MCp2L and LH (LH = catechol, 2,3-dihydroxy-naphthalene and 9,10-phenanthrenediol) were quoted from M.D.M.C. Ribeiro da Silva, Tese de Doutoramento, University of Porto, 1985For L = trans-azobenzene ΔH 0 f(LH,rs) is replaced by ΔH0 f(L,rs)Al-Takhin, Connor, Skinner, Zafarani-Moattar, (1984) J. Organomet. Chem., 260, p. 189 Connor, Zafarani-Moattar, Bickerton, El Saied, Suradi, Carson, Al Takhin, Skinner, (1982) Organometallics, 1, p. 1166 ΔH0 f(CF3CHO,1) is estimated as −810±15 kJ mol−1de M.C. Santos, (1985) Tese de Mestrado, , Data taken from refs. 1, 3, and:, University of Campinas Jorge, Airoldi, Chagas, (1978) J. Chem. Soc., p. 1102. , Dalton Trans de A. Simoni, Chagas, Airoldi, (1980) J. Chem. Soc., p. 156. , Dalton Trans Queiroz, Airoldi, Chagas, Thermochemistry of dichlorobis (triethylphosphine oxide)-zinc(II), -cadmium(II) and -mercury(II), dichloro (triethylphosphine oxide)-mercury(II) and dichlorobis(tribenzylphosphine oxide) -zinc(II) (1981) Journal of Inorganic and Nuclear Chemistry, 43, p. 1207 Airoldi, Chagas, Assunção, (1980) J. Chem. Soc., p. 1823. , Dalton Trans Assunção, Chagas, Airoldi, (1982) J. Chim. 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Temperature-dependence of the liquid viscosities of some phosphorus compounds (1964) Journal of the Chemical Society (Resumed), p. 5144 Vasileva, Zhiltsova, Vvedenskii, (1972) Russ. J. Phys. Chem., 46, p. 315 Luttringhaus, Dirksen, Tetramethylurea as a Solvent and Reagent (1964) Angewandte Chemie International Edition in English, 31, p. 260. , Int. Ed. Engl Gopal, Rizvi, (1968) J. Indian Chem. Soc., 45, p. 13 Suzuki, Onishi, Koide, Seki, Vapor Pressures of Molecular Crystals. XI. Vapor Pressures of Crystalline Urea and Diformylhydrazine. Energies of Hydrogen Bonds in these Crystals (1956) Bulletin of the Chemical Society of Japan, 29, p. 127 (a) J.A. Martinho Simões and J.L. Beauchamp, Chem. Rev., to be publishedTel'noi, Rabinovich, Thermochemistry of Organic Compounds of Transition Metals (1977) Russian Chemical Reviews, 46, p. 689