Artículos de revistas
Insulator-to-metal Transition Driven By Clustering Of Solitons In Polyacetylene
Registro en:
Synthetic Metals. , v. 85, n. 01/03/15, p. 1083 - 1084, 1997.
3796779
2-s2.0-0031069576
Autor
Lavarda F.C.
Galvao D.S.
Laks B.
Institución
Resumen
It's believed that the simple Su-Schrieffer-Heeger Hamiltonian can not predict the insulator to metal transition of transpolyacetylene (t-PA). The soliton lattice configuration at a doping level y=6% still has a semiconductor gap. Disordered distributions of solitons close the gap, but the electronic states around the Fermi energy are localized. However, within the same framework, it is possible to show that a cluster of solitons can produce dramatic changes in the electronic structure, allowing an insulator-to-metal transition. 85 01/03/15 1083 1084 Su, W.P., Schrieffer, J.R., Heeger, A.J., (1980) Phys. Rev., B22, p. 5754 Rice, M.J., Mele, E.J., (1981) Phys. Rev., B23, p. 5397 Su, W.P., (1983) Sol. St. Comm., 47, p. 947 Conwell, E.M., Mizes, H.A., (1989) S. Jeyadev, Phys. Rev., B40, p. 1630 Stafström, S., (1991) Phys. Rev., B43, p. 9158 Cohen, R.J., Glick, A.J., (1992) Phys. Rev. B, 45, p. 3107