Artículos de revistas
Descriptions Of Crystalline Structures Of Zeolites [descrições Estruturais Cristalinas De Zeólitos]
Registro en:
Quimica Nova. , v. 30, n. 1, p. 178 - 188, 2007.
1004042
10.1590/S0100-40422007000100030
2-s2.0-33847751103
Autor
Braga A.A.C.
Morgon N.H.
Institución
Resumen
Crystalline structures of zeolites can be studied using different representations: the internal symmetry obtained by X-Ray or neutron diffraction crystallography techniques or a systematic analysis of the basic structural units which can be arranged to build the geometries of each kind of zeolite. In this work the basic concepts of three building units, SBU (Secondary Building Units), SSU (Structural SubUnits) and PBU (Periodic Building Units) are presented. The properties of the resulting crystalline structures are discussed (pores, cavities, channels), describing the influence of each one of these properties in processes of physical-chemical interest. Representative case studies of known zeolite crystalline structures are also discussed in terms of their space group classification. 30 1 178 188 Sherman, J.D., (1999) Proc. Natl. Acad. Sci. U.S.A, 96, p. 3471 Fujikawa, T., Chiyouda, O., Tsukagoshi, M., Idei, K., Takehara, S., (1998) Catal. Today, 45, p. 307 Park, D.W., Hwang, E.Y., Kim, J.R., Choi, J.K., Kim, Y.A., Woo, H.C., (1999) Polym. Degrad. Stab, 65, p. 193 Anunziata, O.A., Eimer, G.A., Pierella, L.B., (2000) Appl. Catal., A, 190, p. 169 Ribeiro, F. R. Rodrigues, A. E. Rollmann, L. D. Naccache, C. Proceedings of the NATO Advanced Science Institutes Series. Series E, Applied sciences no. 80 - Zeolites: Science and Technology (Alcabideche, Portugal). Martinus Nijhoff Publishers in cooperation with NATO Scientific Affairs Division: Amsterdam, Holanda, 1983Weitkamp, J., (2000) Solid State Ionics, 131, p. 175 Menon, P.G., (1996) Appl. Catal., A, 140, pp. N2 http://www.comciencia.br/reportagens/ framereport.htm, acessada em Dezembro 2005www.zeolyst.com/, acessada em Março 2005Flanigen, E.M., (1991) Em Introduction to Zeolite Science and Practice, , van Bekkum, H, Flanigem, E. M, Jansen, J. C, eds, Elsevier: Amsterdam Coker, E.N., Davis, P.J., Kerkstra, A., van Bekkum, H., (1999) J. Chem. Educ, 76, p. 1417 Pindoria, R.V., Megaritis, A., Herod, A.A., Kandiyoti, R., (1998) Fuel, 77, p. 1715 Haag, W., Lago, R., Weisz, P.B., (1984) Nature, 309, p. 589 Silva, A.O.S., Souza, M.J.B., Aquino, J.M.F.B., Fernandes, V.J., Araujo, A.S., (2004) J. Therm. Anal. Calorim, 76, p. 783 Souza, M.J.B., Silva, A.O.S., Pedrosa, A.M.G., Araujo, A.S., (2005) React. Kinet. Catal. Lett, 84, p. 287 Barcia, P.S., Silva, J.A.C., Rodrigues, A.E., (2005) Microporous Mesoporous Mater, 79, p. 145 De Oliveira, E.C., Pastore, H.O., (2004) Res. Chem. Intermed, 30, p. 857 Sales, M.J.A., Dias, S.C.L., Dias, J.A., Pimentel, T.D., (2005) Polym. Degrad. Stab, 87, p. 153 Nunes, M.H.D., da Silva, V.T., Schmal, M., (2004) Catal. Lett, 97, p. 1 Dias, S.C.L., de Macedo, J.L., Dias, J.A., (2003) Phys. Chem. Chem. Phys, 5, p. 5574 Farneth, W.E., Gorte, R.J., (1995) Chem. Rev, 95, p. 615 Stich, I., Gale, J.D., Terakura, K., Payne, M.C., (1998) Chem. Phys. Lett, 283, p. 402 Haase, F., Sauer, J., (2000) Microporous Mesoporous Mater, 35-36, p. 379 Rabo, J.A., Gajda, G.J., (1990) Catal. Rev. - Sci. Eng, 31, p. 385 Rosenbach, N., Mota, C.J.A., (2005) J. Mol. Struct, 731, p. 157 Lerner, B.A., (1997) Chem. Ind, 1, p. 16 http://www.msi.com/materials/catalysis/zeolite.html, acessada em Março 2005Hafner, J., (2000) Acta Mater, 48, p. 71 Smith, J.V., (1988) Chem. Rev, 88, p. 149 IZA, Newsletter 1, International Zeolite Association, 1977, citado por Edith M. Flanigen, em Introduction to Zeolite Science and Practicehttp://www.iza-online.org, acessada em Março 2005(2005) Gillett2, acessada em, , http://www.foresight.org/Conferences/MNT05/Papers, Março Mellot-Draznieks, C., Girad, S., Ferey, G., (2002) Chem.-Eur. J, 8, p. 4103 Rosi, N., Eddaoudi, M., Kim, J., (2002) Angew. Chem., Int. Ed, 41, p. 284 Draznieks, C.M., Newsam, J.M., Gorman, A.M., (2000) Angew. Chem., Int. Ed, 39, p. 2270 Uzunova, E.L., Nikolov, G.S., (2000) J. Phys. Chem. A, 104, p. 5302 Zhang, J., Li, Z.J., Cheng, J.K., (2005) New J. Chem, 29, p. 421 Huang, Y., (1980) J. Chem. Educ, 57, p. 112 http://olivine.ethz.ch/LFK/software/xrs/dls76manual.html, acessada em Março 2005http://www.iza-structure.org/databases/, acessada em Março 2005van Koningsveld, H., Em ref. 10 Reineke, T.M., Eddaoudi, M., Moler, D., O'Keeffe, M., Yaghi, O.M., (2000) J. Am. Chem. Soc, 122, p. 4843 Eddaoudi, M., Moler, D.B., Li, H., Chen, B., Reineke, T.M., O'Keeffe, M., Yaghi, O.M., (2001) Acc. Chem. Res, 34, p. 319 Guo, W.P., Kong, L.D., Ha, C.S., (2003) Stud. Surf. Sci. Catal, 146, p. 307 Shoemaker, D.P., Robson, H.E., Broussard, L., (1973) Proceedings of the In Third International Conference on Molecular Sieves, Zurich, , American Chemical Society: Zurique (1992) Modelling of Structure and Reactivity in Zeolites, , Catlow, C. R. A, ed, Academic Press: Londres Bu, X., Feng, P., Stucky, G.D., (1998) J. Am. Chem. Soc, 120, p. 11204 Jin, Q., Zhu, S., Sun, P., Li, B., Guo, Z., Ding, D., (1998) J. Mol. Struct, 470, p. 277 http://www.iucr.org/iucr-top, acessada em Março 2005Glusker, J.P., Lewis, M., Rossi, M., (1994) Crystal Structure Analysis for Chemists and Biologists, , VCH Publishers, Inc, New York http://www-structure.llnl.gov/, acessada em Março 2005Baerlocher, C., Meier, W.M., Olson, D.H., (2001) Atlas of Zeolite Framework Types, Fifth Revised Editon, , Elsevier: Amsterdam Giannetto, G., (1989) Zeolitas, , Edit, Editorial Innovación Tecnológica: Caracas Nikolakis, V., Xomeritakis, G., Abibi, A., Dickson, M., Tsapatsi, M., Vlachos, D.G., (2001) J. Memb. Sci, 184, p. 209 Martín-Palma, R. J. Hernández-Vélez, M. Díaz, I. H. Villavicencio-García, M. M. G.-P. Martínez-Duart, J. M. Pérez-Pariente, J. Mater. Sci. Eng., C 2001, 15, 163Meier, W.M., (1978) Nature, 272, p. 437 Chao, K.-J., Lin, J.-C., Wang, Y., Lee, G.H., (1986) Zeolites, 6, p. 35 Wang, X., Jacobson, A.J., (2001) Mater. Res. Soc. Symp. Proc, 658. , GG8.1.1 Olson, D.H., Kokotailo, G.T., Lawton, S.L., Meier, W.M., (1981) J. Phys. Chem, 85, p. 2238 Ogura, M., ya Shinomiya, S., Tateno, J., Nara, Y., Nomura, M., Kikuchi, E., Matsukata, M., (2001) Appl. Catal., A, 219, p. 33 Coker, E. N. Jansen, J. C. DiRenzo, F. Fajula, F. Martens, J. A. Jacobs, P. A. Jr., A. S. Microporous Mesoporous Mater. 2001, 46, 223http://www.chemkeys.com, acessada em Março 2005