Artículos de revistas
The Second Law Of Thermodynamics [a Segunda Lei Da Termodinâmica]
Registro en:
Quimica Nova. , v. 35, n. 5, p. 1057 - 1061, 2012.
1004042
2-s2.0-84864207976
Autor
Reis M.C.
Bassi A.B.M.S.
Institución
Resumen
Considering intrinsic characteristics of the system exclusively, both statistical and information theory interpretations of the second law are used to provide more comprehensive meanings for the concepts of entropy, temperature, and Helmholtz and Gibbs energies. The coherence of Clausius inequality to these concepts is emphasized. The aim of this work is to re-discuss the second law of thermodynamics in accordance to homogeneous processes thermodynamics, a temporal science which is the very special oversimplification of continuum mechanics for spatially constant intensive properties. 35 5 1057 1061 Carnot, N.L.S., (1878) Refléxions sur la Puissance Motrice du Feu et sur les Machines Propres á Développer Cette Puissance, , Gauthier-Villars: Paris Ŝilhavý, M., (1997) The Mechanics and Thermodynamics of Continuous Media, , Springer: Berlin Kestin, K., (1976) The Second Law of Thermodynamics, , Dowden, Hutchinson & Ross: Stroudsburg Serrin, J., (1979) Arch. Ration. Mech. Anal., 70, p. 355 Truesdell, C.A., (1984) Rational Thermodynamics, , 2nd ed., Springer: New York Truesdell, C.A., (1980) The Tragicomical History of Thermodynamics, pp. 1822-1854. , Springer: Heidelberg Shannon, C., (1948) AT&T Tech. J., 27, p. 379 Brillouin, L., (2004) Science and Information Theory, , 2nd ed., Dover: Mineola Fermi, E., (1956) Thermodynamics, , Dover: New York http://chemkeys.com/br/2005/11/18/entropia-e-energias-de-helmholtz-e-de- gibbs, acessada em Dezembro 2011Ben-Naim, A., (2008) A Farewell to Entropy: Statistical Thermodynamics Based on Information, , World Scientific: Toh Tuck Link Reis, M.C., Bassi, A.B.M.S., (2011) Em Thermodynamics, p. 5. , Tadashi, M., ed. Intech: Rijeka, cap Tolman, R.C., (1979) The Principles of Statistical Mechanics, , Dover: New York Debenedetti, P.G., (1996) Metastable Liquids: Concepts and Principles, , Princeton University Press: Princeton http://chemkeys.com/br/2006/04/17/as-duas-expressoes-fundamentais-da- termodinamica, acessada em Novembro 2011Planck, M., (1945) Treatise on Thermodynamics, , 3rd ed., Dover: New York Moreira, N.H., Bassi, A.B.M.S., (2001) Quim. Nova, 24, p. 563 Nery, L.A.R., Bassi, S.A.B.M., (2009) Quim. Nova, 32, p. 522