Artículos de revistas
Enantioselective Reductions Of Ketones Using Baker's Yeast [reduções Enantiosseletivas De Cetonas Utilizando-se Fermento De Pão]
Registro en:
Quimica Nova. , v. 24, n. 6, p. 893 - 897, 2001.
1004042
2-s2.0-0345856603
Autor
Rodrigues J.A.R.
Moran P.J.S.
Institución
Resumen
Baker's yeast has been successful employed to reduce carbonyl compounds carrying appropriated substituents at distances under the electronic influence of the keto group. High yields and enantiomeric excess (ee) were obtained with 1,2-alkanedione, 1,2-alkanedione (2-O-methyloxime) and 1,3-alkanedione. Potential chiral building blocks were obtained and applied for stereoselective synthesis of valuable compounds. Evidence for a free radical chain process was obtained with baker's yeast reduction of a-iodoacetophenone using radical inhibitors. 24 6 893 897 Pasteur, L., (1862) C. R., Hebd. Seances Acad. Sci., 55, p. 28 Brown, A.J., (1886) J. Chem. Soc., 49, p. 172 Boutroux, L., (1880) C. R., Hebd. Seances Acad. Sci., 91, p. 236 Bertrand, G., (1896) C. R., Hebd. Seances Acad. Sci., 122, p. 900 Dumas, J.B., (1874) Ann. Chim. Phys., 5, p. 3 Windisch, W., (1898) Chem. 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