Now showing items 21-30 of 1102
Reply to “Comment on ‘An interesting case where water behaves as a unique solvent: 4-aminophthalimide emission profile to monitor aqueous environment’”
(American Chemical Society, 2013-04)
The role of stereoelectronic interactions in the conformational isomerism of some phosphorus-containing model compounds
(John Wiley & Sons LtdChichesterInglaterra, 2008)
Solvent effect on a model SNAr reaction in ionic liquid/water mixtures at different compositions
The reaction of phenyl 2,4,6-trinitrophenyl ether and piperidine was kinetically evaluated in BMIMBF4/ water mixtures as the reaction media. This study shows the dramatic effect of the mixture composition on the reacting ...
Computer simulations of the solvation dynamics of Coumarin 153 in dimethylsulfoxide
(Elsevier Science BvAmsterdamHolanda, 2003)
Solvatochromic Dipolarity Micro-Sensor Behavior in Binary Solvent Sustems of the (Water + Ionic Liquid) Type. Application of Preferential Solvation Model And Linear Solvation Energy Relationships
The type of specific intermolecular and interionic interactions that are established when an ionic liquid is dissolved in water was here analysed. The study of the solvatochromic response of dipolarity micro-sensors based ...
Substantial improvement of electrocatalytic predictions by systematic assessment of solvent effects on adsorption energies
(Elsevier B.V., 2020-01-01)
Electrocatalytic activities are largely determined by the interplay of adsorbates with substrates and solvents. Although capturing the interactions of those three components is usually arduous, here we provide a simple ...
Solvent Polarity Considerations Are Unable to Describe Fullerene Solvation Behavior
(Amer Chemical Soc, 2014-03-27)
Atomistic molecular dynamics simulations were employed to investigate the solvation properties of the fullerene C-60 in binary water/dimethyl sulfoxide (DMSO) mixtures. Structural analysis indicates a preferential solvation ...
Correlation between solvation of peptide-resins and solvent properties
(Amer Chemical Soc, 1996-12-13)
The solvation properties of model resin and peptide-resins measured in ca. 30 solvent systems correlated better with the sum of solvent electron acceptor (AN) and electron donor (DN) numbers, in 1:1 proportion, than with ...
STANDARD MOLAR ENTHALPIES OF SOLVATION OF ALIPHATIC ESTERS IN 1,2-DICHLOROETHANE AND N-HEXANE
(Plenum Publ CorpNew York, 1993)
A Spectroscopic Model for the Study of Preferential in the Ground and Excited Electronic States.
The preferential solvation of a solute molecule in mixed solvents is analysed in terms of the spectral solvent shifts. A spectroscopic model is developed in order to know the preferential solvation degree in the ground ...