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Prediction of effective reaction rates in catalytic systems of multiple reactions using one-dimensional models
(Elsevier Science Sa, 2018-03)
In this work two one-dimensional (1D) models are used to approximate the catalytic behavior of three-dimensional (3D) shaped pellets. One of the 1D models employs a single parameter and is identified as Generalized Cylinder ...
Understanding the Physics and Chemistry of Reaction Mechanisms from Atomic Contributions: A Reaction Force Perspective
(AMER CHEMICAL SOC, 2012)
Studying chemical reactions involves the knowledge of the reaction mechanism. Despite activation barriers describing the kinetics or reaction energies reflecting thermodynamic aspects, identifying the underlying physics ...
Kinetics and Reaction Mechanism of Biothiols Involved in SNAr Reactions: An Experimental Study
(2022)
Few kinetic parameters, or reaction rates, are known up to date in detail about 1-chloro and 1-fluoro-2,4-dinitrobenzene (ClDNB and FDNB, respectively) with a series of biothiols in aqueous media. These biological nucleophiles ...
Transversal Instability for the Thermodiffusive Reaction-Diffusion System
(Shanghai Scientific Technology Literature, 2015)
The propagation of unstable interfaces is at the origin of remarkable patterns that are observed in various areas of science as chemical reactions, phase transitions, and growth of bacterial colonies. Since a scalar equation ...
Reaction functions for weakly bound systems
(ELSEVIER SCIENCE BV, 2009)
We propose a new technique to analyze total reaction cross sections. In this technique, which has been previously applied to fusion reactions, the experimental data are used to build a dimensionless reaction function, which ...
Kinetics and reaction mechanism of biothiols involved in SNAr reactions: an experimental study
(Frontiers Media, 2022)
Few kinetic parameters, or reaction rates, are known up to date in detail about 1-chloro and 1-fluoro-2,4-dinitrobenzene (ClDNB and FDNB, respectively) with a series of biothiols in aqueous media. These biological nucleophiles ...
Insect Venom Immunotherapy: Analysis of the Safety and Tolerance of 3 Buildup Protocols Frequently Used in Spain
Introduction: Hymenoptera venom immunotherapy (VIT) is an effective treatment but not one devoid of risk, as both local and systemic adverse reactions may occur, especially in the initial phases. We compared the tolerance ...
Synthetic silica nano-organelles for regulation of cascade reactions in multi-compartmentalized systems
(Wiley VCH Verlag, 2022-02)
In eukaryotic cells, enzymes are compartmentalized into specific organelles so that different reactions and processes can be performed efficiently and with a high degree of control. In this work, we show that these features ...