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Organic synthesis in water mediated by silyl radicals
(Bentham Science Publishers, 2011-06)
This account is focused on highlighting the recent advances on synthetically-useful organic reactions employing siliconcentered radicals in water, and presenting new reactions in water, mediated by silyl radicals. In doing ...
Organic Synthesis in Water Mediated By Silyl Radicals
(Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2011)
This account is focused on highlighting the recent advances on synthetically-useful organic reactions employing siliconcentered radicals in water, and presenting new reactions in water, mediated by silyl radicals. In doing ...
(Me3Si)3SiH-mediated intermolecular radical perfluoroalkylation reactions of olefins in water
(American Chemical Society, 2010-09)
Figure presented. Perfluoroalkyl-substituted compounds are regarded as important components of fluorophors and for the introduction of fluorous tags into organic substrates. Their syntheses in organic solvents are achieved ...
Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
(Wiley, 2010-10)
The classical radical-based hydrosilylation reaction of organic compounds bearing C[BOND]C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic ...
Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
(Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2010)
The classical radical-based hydrosilylation reaction of organic compounds bearing C C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic substrates. ...
Monolayers and Thin Films of Dextran Hydrophobically Modified
(SOC BRASILEIRA QUIMICA, 2010)
A series of biodegradable graft copolymers were synthesized by grafting epsilon-caprolactone over dextran of different molecular weights. The obtained copolymers were characterized by Fourier transform infrared spectroscopy ...
(Me3Si)3SiH-Mediated Intermolecular Radical Perfluoroalkylation Reactions of Olefins in Water
(Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2010)
Perfluoroalkyl-substituted compounds are regarded as important components of fluorophors and for the introduction of fluorous tags into organic substrates. Their syntheses in organic solvents are achieved through different ...