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Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
(Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2010)
The classical radical-based hydrosilylation reaction of organic compounds bearing C C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic substrates. ...
Organic Synthesis in Water Mediated By Silyl Radicals
(Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2011)
This account is focused on highlighting the recent advances on synthetically-useful organic reactions employing siliconcentered radicals in water, and presenting new reactions in water, mediated by silyl radicals. In doing ...