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Ion transfer across liquid|liquid interface under forced hydrodynamic conditions. I: Digital simulations
(Elsevier Science Sa, 2012-02)
In this paper, we present the general equations for a model that describes ion transfer reactions across the oil|water interface assisted by a ligand, under forced hydrodynamic conditions. Our analysis is mainly focused ...
Designing and understanding permanent microporosity in liquids
(Royal Society of Chemistry, 2014-03)
Standard microporous materials are typically crystalline solids that exhibit a regular array of cavities of uniform size and shape. Packing and directional bonding between molecular building blocks give rise to interstitial ...
Facilitated anion transfer reactions across oil∣water interfaces
(Elsevier Science Sa, 2010-05)
In this paper we present the general equations for a model of anion transfer reactions across the oil{divides}water interface assisted by a neutral ligand. Our analysis mainly focuses on the effect of water autoprotolysis. ...
Specific Heat Anomaly in a Supercooled Liquid with Amorphous Boundary Conditions
(American Physical Society, 2015-06)
We study the specific heat of a model supercooled liquid confined in a spherical cavity with amorphous boundary conditions. We find the equilibrium specic heat has a cavity-size-dependent peak as a function of temperature. ...
Thermodynamics, transition dynamics, and texturing in polymer-dispersed liquid crystals with mesogens exhibiting a direct isotropic/smectic-A transition
(American Chemical Society, 2009-12-23)
Experimental and modeling/simulation studies of phase equilibrium and growth morphologies of novel polymer-dispersed liquid crystal (PDLC) mixtures of PS (polystyrene) and liquid crystals that exhibit a direct isotropic/smectic-A ...
Spinodals and critical point using short-time dynamics for a simple model of liquid
(American Institute of Physics, 2016-04)
We have applied the short-time dynamics method to the gas-liquid transition to detect the supercooled gas instability (gas spinodal) and the superheated liquid instability (liquid spinodal). Using Monte Carlo simulation, ...
CFD-DEM modeling of solid motion in a water-calcium alginate fluidized column and its comparison with results from radioactive particle tracking
(Elsevier Science Sa, 2019-12)
The motion of calcium alginate spheres in a liquid-solid fluidized bed is examined by radioactive particle tracking (RPT) and simulated by computational fluid dynamics coupled with discrete element method (CFD-DEM). ...
Effective diffusion coefficient for Cu in steel joined by transient liquid phase bonding
(Elsevier, 2016-02)
Seamless carbon steel tubes were joined by the transient liquid phase (TLP) bonding process using Cu foilsas interlayers. Bonding was performed at 1300 °C for 7 min with an applied uniaxial pressure of 5 MPa. Thecompletion ...
Validation of CFD-DEM simulation of a liquid–solid fluidized bed by dynamic analysis of time series
(Elsevier Science Inc., 2022-09)
Liquid–solid fluidized beds (LSFB) modeling validation is crucial for establishing design rules and monitoring tools. However, it generally relies on comparing global variables, which overlook dynamic features that influence ...
Facilitated proton transfer across liquid | liquid interfaces under forced hydrodynamic conditions. Determination of partition coefficients of neutral weak bases
(Elsevier Science Sa, 2017-04)
A novel quantitative methodology to determine the partition coefficients of neutral weak bases is developed. This new electrochemical approach is based on the measurement of the total transferred charge across the oil | water ...