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Radical amination with trimethylstannylated benzophenone imine
(American Chemical Society, 2010-04)
Intermolecular radical amination reactions of various primary, secondary, and tertiary alkyl radicals by using trimethylstannylated benzophenone imine A as a novel radical acceptor to provide imines of type B are described. ...
Cascade cyclization triggered by imine formation. Formal synthesis of the alkaloid (±)-stemoamide and its 9a-epimer
(Elsevier, 2015-10)
A concise formal synthesis of stemoamide ( 1) and its 9a-epimer 14in 5 steps is described featuring a cas-cade cyclization triggered by imine formation. A good selectivity for either epimer is readily accom-plished by ...
New active-iron based reducing system for carbonyl compounds and imines. Stereoselective reduction of cyclic ketones
(Elsevier Science, 2006-03-20)
The reaction of different carbonyl compounds and imines with a mixture of iron(II) chloride tetrahydrate, an excess of lithium powder, and a catalytic amount of 4,4′-di-tert-butylbiphenyl (DTBB, 5 mol%) in THF at room ...
1,3-Dipolar cycloaddition of nitrile imines with alpha,beta-unsaturated lactones, thiolactones and lactams: synthesis of ring-fused pyrazoles
(PERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND, 2012)
Imine bonding self-repair hydrogels after periodate-triggered breakage of their cross-links
(Pergamon-Elsevier Science Ltd, 2020-11)
The development of new materials with smart properties is currently expanding the development of new technologies. Therefore, the design of materials with novel sensitivities and smart behavior is important for the development ...
Photoredox-mediated aminoalkylation and carbamoylation of azomethine imines
(Universidade Federal de São CarlosUFSCarPrograma de Pós-Graduação em Química - PPGQCâmpus São Carlos, 2021-08-25)
Over the past decade, the organic synthetic community has witnessed the emergence of a new and complementary approach to the conventional radical chemistry. Photochemistry has proven to be a powerful and more sustainable ...
Bioreduction of beta-carboline imines to amines employing Saccharomyces bayanus
(PERGAMON-ELSEVIER SCIENCE LTD, 2010)
beta-Carboline imine reductions mediated by Saccharomyces bayanus have been described achieving moderate to good enantiomeric excesses of the amine products. The enantiomeric excesses of the bioreduction showed a dependence ...