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Asymmetric hydroformylation of vinyl arenes catalyzed by furanoside diphosphinites-Rh(I) complexes
(2005-03-30)
Diphosphinite ligands 2 and 3, easily prepared from inexpensive D(+)-xylose in few steps, were tested in the Rh-catalyzed asymmetric hydroformylation of several vinyl arenes. High regio-selectivities in branched aldehyde ...
Influence of the bite natural angle of bidentate diphosphine ligands in the syngas-free branched hydroformylation of Β-functionalized olefins
(Elsevier B.V., 2018)
© 2018 Elsevier B.V. The correlation between the activity, regio- and chemoselectivity of Rh-diphosphine catalyst and the ligand bite natural angle (βn) in the syngas-free hydroformylation of allyl cyanide was investigated. ...
Propene hydroformylation reaction catalyzed by HRh(CO)(BISBI): a thermodynamic and kinetic analysis of the full catalytic cycle
(Universidade Federal de Minas GeraisBrasilICX - DEPARTAMENTO DE QUÍMICAUFMG, 2020)
Hydroformylation of 1-hexene catalyzed by nickel systems containing phosphines as ancillary ligand(Hydroformylation of 1-hexene with nickel systems): Hidroformilación de 1-hexeno catalizada por sistemas de níquel conteniendo fosfinas como ligandos espectadores(Hidroformilación de 1-hexeno con sistemas de níquel)Hidroformilación de 1-hexeno catalizada por sistemas de níquel conteniendo fosfinas como ligandos espectadores(Hidroformilación de 1-hexeno con sistemas de níquel): Hydroformylation of 1-hexene catalyzed by nickel systems containing phosphines as ancillary ligand(Hydroformylation of 1-hexene with nickel systems)
(Facultad Experimental de Ciencias de la Universidad del Zulia, 2021)
Synthesis of indole derivatives by domino hydroformylation/indolization of 2-nitrocinnamaldehydes
(ELSEVIER SCIENCE BV, 2008)
The present work furnishes an innovative preparation of substituted indoles based on tandem hydroformylation, where the chemo- and the regio-selectivities are good, so the yield of the reaction. The novelty has been ...
New aldehydes by catalytic diene cycloisomerisations
(2008)
The Rh-catalysed hydroformylation of isopropylidenecyclohexane derivatives obtained by intramolecular diene cyclisations affords the corresponding aldehydes in good yields and in a completely chemo- and regioselective ...
HYDROFORMYLATION OF ALPHA-PINENE AND BETA-PINENE CATALYZED BY RHODIUM AND COBALT CARBONYLS
(Elsevier Science BvAmsterdamHolanda, 1993)