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Electrocatalysis: Fundamentals and Applications
(Hindawi Publishing Corporation, 2012-04)
Electrocatalysis is a special field in Electrochemistry that hasgained a special growth after the late eighties due to theapplication of new hybrid techniques. However, most of theapplications have run for academic purposes ...
Hydrogen electrocatalysis on overlayers of rhodium over gold and palladium substrates - More active than platinum?
(Royal Society of Chemistry, 2011-09)
We have investigated the stability and catalytic activity of epitaxial overlayers of rhodium on Au(111) and Pd(111). Both surfaces show a strong affinity for hydrogen. We have calculated the energy of adsorption both for ...
A gas-diffusion gold-ring tip: Fabrication, characterization, and application in Electrocatalysis
(Elsevier Science Inc, 2009-07)
A gas-diffusion gold-ring microelectrode used as scanning electrochemical microscopy tip was fabricated. Compared to the ring-tip for droplet dispensation reported before, the as sa-fabricated micropipette tip has a larger ...
Spin effects in oxygen electrocatalysis: a discussion
(Elsevier Science, 2013-04)
The reduction of molecular oxygen in triplet and singlet spin states at metal electrodes is analyzed in the framework of quantum mechanical theory of charge transfer. Both outer- and inner-sphere mechanism is considered. ...
Electrocatalysis of oxygen reduction at electrodeposited molybdenum phosphate-based films
(Elsevier Science, 2012-04)
This work reports an electrode material containing molybdenum phosphate that shows a very interesting behavior as an electrocatalyst for the reduction of oxygen to water (ORR) in acid medium. The material is electrodeposited ...
Improved electrocatalysis and electrophoretic deposition due to the strong synergy between Au and Ag nanoparticles
(Wiley Blackwell Publishing, Inc, 2020-08-21)
Here we demonstrate that every time Au and Ag NPs are physically mixed together they outperform their monometallic counterparts upon electrocatalysis of hydroquinone (HQ) and electrophoretic deposition (EPD) coverage.We ...
Structure, electrocatalysis and dynamics of immobilized cytochrome PccH and its microperoxidase
(Royal Society of Chemistry, 2017-03)
Geobacter sulfurreducens cells have the ability to exchange electrons with conductive materials, and the periplasmic cytochrome PccH plays an essential role in the direct electrode-to-cell electron transfer in this bacterium. ...
Adsorption of 4,4′-Dithiodipyridine Axially Coordinated to Iron(II) Phthalocyanine on Au(111) as a New Strategy for Oxygen Reduction Electrocatalysis
(Wiley VCH Verlag, 2018-07)
The coordination of PySSPy to FePc was monitored by UV/Vis spectroscopy while the adsobed FePc, anchored by PyS−Au(111), was examined by in situ STM in 0.1 M HClO4 and X-ray photoelectron spectroscopy (XPS). Rotating-dis ...