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Thermal behaviour of binuclear cyclopalladated compounds containing anionic azo-ligands
(Editora Unesp, 2002-01-01)
This paper deals with the thermal behavior study of cyclopalladated complexes obtained from reactions of [Pd(dmba)N-3](2) (1), dmba = N,N-dimethylbenzylamine, with azole-compunds, such as, the anionic ligands pyrazolate ...
C-2, N-dimethylbenzylamine cyclopalladated compounds: evaluation of cytotoxic, mutagenic and antitubercular activities
(Springer, 2015-07-01)
Mono- and binuclear cyclometallated Pd(II) compounds containing C,N-chelating dimethylbenzylamine (Hdmba) have been synthesized aiming at investigating their mutagenic properties (Ames test) and cytotoxic activity toward ...
SYNTHESIS; CHARACTERIZATION AND CYTOTOXIC ACTIVITY EVALUATION OF CYCLOPALLADATED COMPOUNDS CONTAINING ORTHOMETALLATED BENZALDEHYDEOXIME AND ETHYLENETHIOUREA AS LIGANDS
(Soc Brasileira Quimica, 2018-12-01)
The halide bridge cleavage reaction of the [Pd(C-2,N-bzox)(mu-Cl)](2). compound (bzox = benzaldehydeoxime) with ethylenethiourea (L) in the 1:2 molar ratio at room temperature yielded the cyclopalladated compound ...
Self-assembly of cyclometallated Pd(II) compounds directed by C-H center dot center dot center dot pi interactions: A structural evidence for metalloaromaticity in a cyclopalladated ring
(Elsevier B.V., 2011-01-01)
Structural studies on the two binuclear cyclometallated compounds [Pd(C-2,N-bzan)(mu-N-3)](2) (1) and [Pd(C-2,N-bzan)(mu-Pz)](2) (2) (bzan = N-benzylideneaniline) have been carried out in this work. In both compounds, C-H ...
Antiprotozoal activity of the cyclopalladated complexes against leishmania amazonensis and trypanosoma cruzi
(2016-06-01)
The present study describes the antiprotozoal activities of four cyclopalladated compounds, [Pd(dmba)(μ-Cl)]2 , [Pd(dmba)(NCO)(isn)], [Pd(dmba)(N3)(isn)] and [Pd(dmba)(μ-NCO)]2 , (dmba: N,N'-dimethylbenzylamine and isn: ...
Asymmetric and Symmetric Triazenido Cyclopalladated Complexes: Synthesis, Structural Analysis and DFT Calculations
(2014)
The reaction of [Pd{dmba}(l-N3)]2 (dmba = N,N-dimethylbenzylamine) with 1-(2-fluorophenyl)-3-(4- nitrophenyl)triazenido (L1 ) or 1,3-bis(4-nitrophenyl)triazenido (L2 ) anions, in methanol, and subsequent treatment with ...