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The relevance of the fluorine interactions in the supramolecular structure of a complex constructed from copper(II) hexafluoroacetylacetonate and the 40-(3-pyridyl)-2,20:60,200-terpyridine ligand. Novel C–F/p synthons involving the p-system of the terpyridine moieties and those of the hexafluoroacetylacetonate chelate rings
(ELSEVIER, 2010)
Reaction of 40-(3-pyridyl)-2,20:60,200-terpyridine (pyterpy) with Cu(hfacac)2 (hfacac = hexafluoroacetylacetonate)
led to the formation of the novel compound [Cu3(hfacac)4(m-pyterpy)2][Cu(hfacac)3]2 (1).
The structure ...
Structure and spectroscopy of two new bases for building block: Terpyridine derivatives
(Elsevier Science, 2015-12)
Two new terpyridine compounds are reported: 4′-(3-methyl-2-thienyl)-4,2′:6′,4″-terpyridine, C20H15N3S, (I) and 4′-(4-quinolinyl)-4,2′:6′,4″-terpyridine, C25H17Cl3N4, (II). Both structures crystallize in centrosymmetric ...
Design and spectroscopic study of new ruthenium(II) complexes containing ligands derived front terpyridine and dipyrido[3,2-a:2′,3′-c] phenazine: Ru(4′ -Rph-tpy) [dppz(COOH)]Cl}PF6 with R = NO 2, Br, Cl
(2006)
A series of polypyridine ruthenium complexes of the general formula {Ru(Rph-tpy)[dppz(COOH)]Cl} PF6 with R = Br (1), Cl (2), NO 2 (3) where Rph-tpy is 4′-(4-Rphenyl-2,2′:6′, 2″-terpyridine and dppz(COOH) is dipyrido[3,2-a:2′,3′-c] ...
Hydrogen bonding and p-stacking interactions in the zipper-like supramolecular structure of the monomeric cadmium(II) complex [Cd(pyterpy)(H2O)(NO3)2] (pyterpy = 4’-(4-pyridyl)-2,2’:6’,2’’-terpyridine)
(2004)
The reaction of pyterpy with an excess of cadmium(II) nitrate yields the novel mononuclear complex [Cd(pyterpy)(H2O)(NO3)(2)]. The crystal structure shows to the Cd(II) centre in a seven-coordinate environment and the ...
Design and spectroscopic study of new ruthenium(II) complexes containing ligands derived from terpyridine and dipyrido[3,2-a : 2 ',3 '-c]phenazine: {Ru(4 '-Rph-tpy)[dppz(COOH)]Cl}PF6 with R=NO2, Br, Cl
(JOHN WILEY, 2006-05)
A series of polypyridine ruthenium complexes of the general formula [Ru(Rph-tpy)[dppz(COOH)]Cl) PF6 with R = Br (1), Cl (2), NO2 (3) where Rph-tpy is 4'-(4-Rphenyl-2,2':6',2"-terpyridine and dppz(COOH) is dipyrido[3,2-a: ...
The novel ligand 4 '-phenyl-3,2 ':6 ',3 ''-terpyridine (L) and the supramolecular structure of the dinuclear complex [Zn-2(mu-L)(acac)(4)] center dot H2O (acac = acetylacetonato)
(ELSEVIER, 2008-11)
The new terpyridyl ligand 4'-phenyl-3,2':6',3 ''-terpyridine (L) reacts with Zn(acac)(2) to produce the dizinc complex [Zn-2(mu-L)(acac)(4)] center dot H2O (1) (acac = acetylacetonato). The analysis of the crystal structure ...