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Infrared multiphoton dissociation of SiF4: Gas phase reactions of SiF3 with F and H2
(Elsevier Science Sa, 2004-07)
The infrared multiphoton dissociation (IRMPD) of pure SiF4 and in mixtures with different gases was studied using a tunable CO2 TEA laser. The initial dissociation step of the IRMPD of SiF4 was found to be the decomposition ...
SiF4 IR Photodissociation: Gas phase reactions of SiF3 with CH4
(Elsevier Science Sa, 2009-06)
The infrared multiphoton dissociation (IRMPD) of SiF4 in the presence of CH4 has been studied using a tunable CO2 TEA laser. The siliconated reaction products have been identified. A kinetic scheme has been proposed to ...