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Síntese de copolímeros em bloco por reações one-pot com processos RAFT e ROP simultâneos
(Universidade Federal de Santa MariaBRQuímicaUFSMPrograma de Pós-Graduação em Química, 2016-02-04)
The present work describes a methodology of controlled synthesis of block copolymers by one-pot reactions involving simultaneous RAFT and ROP processes mediated by a bifunctional compound which acts as a chain transfer ...
Controlled One-Pot Synthesis of Polystyrene-block-Polycaprolactone Copolymers by Simultaneous RAFT and ROP
(Wiley, 2013-08)
A convenient one-pot method for the controlled synthesis of polystyrene- block -polycaprolactone (PS- b -PCL) copolymers by simultaneous reversible addition?fragmentation chain transfer (RAFT) and ring-opening polymerization ...
Facile one-pot synthesis and solution behavior of poly(acrylic acid)-block-polycaprolactone copolymers
(Elsevier Science, 2019-01)
A metal-free protocol to obtain poly(acrylic acid)-block-polycaprolactone diblock copolymers (PAA-b-PCL) by a one-pot method involving simultaneous Reversible Addition-Fragmentation Chain Transfer (RAFT) and Ring Opening ...
Synthesis of Grafted Block Copolymers Based on e-Caprolactone: Influence of Branches on Their Thermal Behavior
(Wiley Vch Verlag, 2015-11-17)
Branched copolymers are a special class of polymeric materials in which are refl ected the combined effects of polymer segments and architectural constraints of the branched architecture. This study employed two methodologies ...
Tailor-made, linear, and “comb-like” polyester-based copolymers: Synthesis, characterization, and thermal behavior of potential 3D-printing/electrospinning candidates
(Hindawi Publishing Corporation, 2018-10)
Tailor-made, linear, and “comb-like” poly(ε-caprolactone)-based copolymers were synthesized by employing a combination of controlled polymerization techniques. Poly(dimethylsiloxane-block-ε-caprolactone) copolymers (SCL#) ...