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Hydrosilylation of C−C Multiple Bonds Using (Me3Si)3SiH in Water. Comparative Study of the Radical Initiation Step
(Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2009)
The classical radical-based hydrosilylation reaction of organic compounds bearing C−C multiple bonds is usually carried out in organic solvents and is herein presented in water with both organic solvent-soluble and ...
Hydrosilylation of C-C multiple bonds using (Me3Si) 3SiH in water: Comparative study of the radical initiation step
(American Chemical Society, 2009-06)
The classical radical-based hydrosilylation reaction of organic compounds bearing C-C multiple bonds is usually carried out in organic solvents and is herein presented in water with both organic solventsoluble and water-soluble ...
Antioxidant capacity of diethyldithiocarbamate in a metal independent lipid peroxidative process
(1989)
2,2′-Azobis-[2-amidinopropane] initiated lipid peroxidation of egg yolk phosphatydil choline liposomes was measured by oxygen uptake and the emitted visible luminescence. Lipid peroxidation involved a chain process (kinetic ...
Thermal Decomposition Reaction of Pinacolone Diperoxide: its Use as Radical Initiator in the Styrene Polymerization
(Springer, 2017-09)
Some commercial vinyl polymers such as polystyrene, polymethylmethacrylate and polyvinyl chloride have been synthetized through last years using new initiators, for example those with multiple active sites. Multifunctional ...
Unexpected Imidazoquinoxalinone Annulation Products in the Photoinitiated Reaction of Substituted-3-Methyl-Quinoxalin-2-Ones with N-Phenylglycine
(The American Society of Photobiology, 2013)
Photoinduced electron transfer between N-phenylglycine
(NPG) and electronically excited triplets of 7-substituted-3-
methyl-quinoxalin-2-ones in acetonitrile generate the respective
ion radical pair, where by decarboxylation ...
DFT study on the molecular mechanism of the [4 + 2] cycloaddition between thiobenzophenone and arylalkenes via radical cations
(American Chemical Society, 2009-05)
The mechanistic aspects of the radical cationic version of the [4 + 2] cycloaddition between thiobenzophenone 1 and three aryl-substituted alkenes 2a-c have been studied using DFT methods at the UB3LYP/6-31G level of theory. ...
Cinética y mecanismos de reacción de radicales estables con sustratos de interés biológico
(Universidad de Chile, 2000)
El radical catiónico derivado del ácido 2,2'-Azinobis(3-etilbenzotiazolin-6-
sulfónico) (ABTS) ha sido ampliamente utilizado como método para evaluar tanto la
presencia como 1a capacidad antioxidante en sistemas biológicos. ...
Low Dispersity and High Conductivity Poly(4-styrenesulfonic acid) Membranes Obtained by Inexpensive Free Radical Polymerization of Sodium 4-styrenesulfonate
(MDPICiencia de los MaterialesBasilea, Suiza, 2021)
Unraveling the degradation mechanism of purine nucleotides photosensitized by pterins: the role of charge-transfer steps
(Royal Society Of Chemistry, 2015-04)
Photosensitized reactions contribute to the generation of skin cancer and are used in many applications. The photosensitizers may act through different mechanisms. It is currently accepted that if the photosensitizer ...
Polymerization Rate Modulated by Tetraarylborate Anion Structure: Direct Correlation of Hammett Substituent Constant with Polymerization Kinetics of 2-Hydroxyethyl Methacrylate
(2018-10-23)
A series of para-substituted tetraarylborates were investigated as aryl radical generator for photopolymerization reactions, using 2-hydroxyethyl methacrylate as monomer. The first steps of the photopolymerization process ...