The use of the adjective radical to identify the variety of behaviorism proposed by Skinner is current nowadays. However, historically, this qualifier was not exclusively applied to Skinner's proposal and its polysemy tends ...

This account is focused on highlighting the recent advances on synthetically-useful organic reactions employing siliconcentered radicals in water, and presenting new reactions in water, mediated by silyl radicals. In doing ...

This account is focused on highlighting the recent advances on synthetically-useful organic reactions employing siliconcentered radicals in water, and presenting new reactions in water, mediated by silyl radicals. In doing ...

This account is focused on carbon-carbon, and carbon-sulphur bond-forming reactions through the use of carbon- and sulphur-centred radicals in water, respectively. It intends to show the scope and applications on these ...

Figure presented. Perfluoroalkyl-substituted compounds are regarded as important components of fluorophors and for the introduction of fluorous tags into organic substrates. Their syntheses in organic solvents are achieved ...

Fluorinated radicals in water are shown to enable a useful array of synthetic organic transformations, reflecting these intermediates' distinct behavior in water or aqueous media. The enhanced reactivities of perfluroalkyl ...

This chapter reports on radical arylations also highlighting the very important early achievements on this chemistry. To be named at this place are the Meerwein arylation and the Pschorr reaction. Intramolecular homolytic ...