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Organic synthesis in water mediated by silyl radicals
(Bentham Science Publishers, 2011-06)
This account is focused on highlighting the recent advances on synthetically-useful organic reactions employing siliconcentered radicals in water, and presenting new reactions in water, mediated by silyl radicals. In doing ...
Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous media
(Royal Society of Chemistry, 2011-07)
This account is focused on carbon-carbon, and carbon-sulphur bond-forming reactions through the use of carbon- and sulphur-centred radicals in water, respectively. It intends to show the scope and applications on these ...
Reactivity of fluorinated organic radicals in aqueous media
(Wiley VCH Verlag, 2012-04)
Fluorinated radicals in water are shown to enable a useful array of synthetic organic transformations, reflecting these intermediates' distinct behavior in water or aqueous media. The enhanced reactivities of perfluroalkyl ...
ESTIMATION OF HYDROXYL AND HYDROPEROXYL RADICALS CONCENTRATIONS IN THE URBAN ATMOSPHERE OF SANTIAGO
(Sociedad Chilena de Química, 2005)
Em que sentido(s) é radical o Behaviorismo Radical?
The use of the adjective radical to identify the variety of behaviorism proposed by Skinner is current nowadays. However, historically, this qualifier was not exclusively applied to Skinner's proposal and its polysemy tends ...
Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
The classical radical-based hydrosilylation reaction of organic compounds bearing C[BOND]C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic ...
Spectral and kinetic properties of radicals derived from oxidation of quinoxalin-2-one and its methyl derivative
(MDPI AG, 2014)
© 2014 by the authors licensee MDPI Basel Switzerland.The kinetics and spectral characteristics of the transients formed in the reactions of • OH and •N3 with quinoxalin-2(1H)-one (Q), its methyl derivative, 3-methylquinoxalin- ...
SYNTHESIS OF CHROMANOLS BY TANDEM RADICAL ADDITION/CYCLIZATION MEDIATED BY TRIS(TRI METHYLSILYL)SILANE
(Sociedad Chilena de Química, 2007)