We review the origins of capacitive phenomena at the nanoscale to demonstrate that electrochemistry cannot be understood without a critical re-reading of nanoscale electronics, and vice-versa. The fundamentals are stated ...

The merging of nanoscale electronics and electrochemistry can potentially modernize the way electronic devices are currently engineered or constructed. This Feature offers a conceptual discussion of this central topic, ...

Los estudios realizados en este trabajo abarcan diferentes aspectos de la cinética de la reacción de desprendimiento de hidrógeno (her). Esto tiene como finalidad la obtención de nuevos conocimientos que permitan comprender ...

The concept of electrochemical capacitance comprises both double-layer grounded capacitive (non-faradaic charging) and pseudocapacitive (faradaic charging) behaviours, as has been recently demonstrated [1–3]. In this paper, ...

Here, we demonstrate that impedance-derived capacitance spectroscopy is a useful method for measuring and analyzing the quantum of conductance and capacitance of a single-layer graphene sheet. Both quantum conductance and ...

In Chap. 1, we demonstrated that nanoscale electronics and electrochemistry both originate from the same physical background and are underpinned by chemical capacitance and its association with quantised relaxation resistance, ...

A thermodynamic model predicting the disappearance of the underpotential deposition phenomenon in the limit of small nanoparticles is proposed and developed for selected families of geometric bodies. The key parameters are ...

Gas-producing electrochemical reactions are key to energy conversion and generation technologies. Bubble formation dramatically decreases gas-production rates on nanoelectrodes, by confining the reaction to the electrode ...