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Complexes of macrocycles with pendant arms as models for biological molecules
(Elsevier, 2000)
Recent literature results on inorganic models related to metalloenzymes which transport electrons or activate small molecules are discussed in this review. The molecular systems are essentially restricted to macrocyclic ...
Synthesis and characterization of a new polyaminocarboxylic macrocyclic ligand and its non-ion gadolinium complex. In vitro relaxivity studies at 0.2 T
(Elsevier Science, 2015-01)
In this study a novel ligand with three carboxylic groups (H3L1 ) was synthesized. Its non-ion complex with GdL1 holding promise of magnetic resonance imaging (MRI) was synthesized, and the relaxivity of the complex ...
Contribution of the ligand to the electroreduction of co2 catalyzed by a cobalt(ii) macrocyclic complex
(GORDON AND BREACH SCIENCE PUBLISHERS, 2003)
Solid state photoluminescence studies of [EuLnH2(NO3)3](H2O)x macrocyclic complexes with Schiff base ligands
(Elsevier B.V., 2018)
Three EuIII macrocyclic complexes [EuLnH2(NO3)3](H2O)x based on the ligands derived from 2-hydroxy-5-methyl-1,3-benzenedicarbaldehyde and three different amines: o-phenylenediamine, Eu-OPDA; ethylenediamine, Eu-EDA; and ...
Magnetic properties of composites based on the intercalation of ZnII and CuII bimetallic macrocyclic complexes in the MnPS3 phase
(RSC Advances, 2017)
Asymmetric macrocyclic complexes of the type [M2LCl2]·xH2O have been obtained and intercalated using the potassium precursor phase K0.4Mn0.8PS3·H2O (M: ZnII or CuII; LH2: macrocyclic ligand derived from 2-hydroxy-5-methy ...
A non-ionic gadolinium complex whose relaxometric behavior is sensitive to the variation of pH: An experimental and theoretical study on geometry, bonding nature of polyaminocarboxylic ligand and their gadolinium complex
(Bentham Science Publishers, 2018-10)
Background: In addition, the contribution of cyclic structure to the stability of lanthanide complexes has been evaluated on different ligand platforms and some indications of their relative stability are now available. ...
Synthesis, characterization and kinetic studies of the cis-[RuCl2(cyclen)]+ complex
(2002-01-30)
We report here the synthesis, characterization and kinetic studies of cis-[RuCl2(cyclen)]+ in aqueous solution, where cyclen is the macrocyclic ligand 1,4,7,10-tetraazacyclododecane. The complex releases one Cl− producing ...