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Solid-supported cross-metathesis and a formal alkane metathesis for the generation of biologically relevant molecules
(American Chemical Society, 2015-02)
Solid-phase synthetic strategies towards the generation of libraries of biologically relevant molecules were developed using olefin cross-metathesis as a key step. It is remarkably the formal alkane metathesis based on a ...
Cross-Metathesis on Immobilized Substrates – Application to the Generation of Synthetically and Biologically Relevant Structures
(Wiley VCH Verlag, 2017-04)
Olefin metathesis constitutes a seemingly endless area of research that has had an enormous impact on several branches of chemistry, both in industry and in academia. Once the potential of this reaction as a carbon–carbon ...
Vowel-consonant metathesis in Nivaĉle
(Cambridge University Press, 2020-05)
Vowel-consonant metathesis is observed in a variety of contexts throughout the Nivaĉle (Mataguayan) grammar. It occurs in both verbal and nominal domains, characteristically resulting from the affixation of a consonant-initial ...
A comparative study of hydrosilane compounds as cocatalysts in the metathesis of 1-hexene
(Elsevier B.V., 1998-12-21)
The selectivity of I-hexene metathesis using WCI6 as catalyst was evaluated with a series of hydrosilane-compounds as cocatalysts: Ph3SiH, Ph2SiH2, PhSiH3 and polymethylhydrosiloxane (PMHS). The metathesis reaction is ...
A comparative study of hydrosilane compounds as cocatalysts in the metathesis of 1-hexene
(Elsevier B.V., 1998-12-21)
The selectivity of I-hexene metathesis using WCI6 as catalyst was evaluated with a series of hydrosilane-compounds as cocatalysts: Ph3SiH, Ph2SiH2, PhSiH3 and polymethylhydrosiloxane (PMHS). The metathesis reaction is ...
Valorisation of plant oil derivatives via metathesis reactions: study of the cross-metathesis of methyl oleate with cinnamaldehyde
(Elsevier, 2020-02)
The cross-metathesis of methyl oleate (MO) with cinnamaldehyde (CA) to yield 2-undecenal, methyl 11-oxo-9-undecenoate, methyl 10-phenyl-9-decenoate and 1-decenylbenzene was investigated using the second-generation ...
Valorisation of vegetable oils by heterogeneous catalysis via metathesis reactions
(Elsevier B.V., 2018-04)
The metathesis of unsaturated fatty acid methyl esters (FAME) to obtain value-added chemicals is becoming increasingly attractive in oleochemistry. Nevertheless, there is a need to develop efficient solid catalysts for ...
Unravelling the olefin cross metathesis on solid support. Factors affecting the reaction outcome
(Royal Society of Chemistry, 2010-06)
Olefin cross metathesis on solid support under a variety of conditions is described. A comprehensive analysis considering diverse factors governing the reaction outcome gives a series of patterns for the application of ...