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Atmospheric degradation of industrial fluorinated acrylates and methacrylates with Cl atoms at atmospheric pressure and 298 K
(Pergamon-Elsevier Science Ltd, 2018-04)
The gas-phase reaction of Cl atom with 2,2,2-trifluoroethylacrylate (k1), 1,1,1,3,3,3-hexafluoroisopropylacrylate (k2), 2,2,2-trifluoroethylmethacrylate (k3) and 1,1,1,3,3,3-hexafluoroisopropylmethacrylate (k4), have been ...
Kinetics of the reactions of Cl atoms with CF3C(O)OCH3, CF3C(O)OCH2CH3, CF2HC(O)OCH3 in the temperature range of 287-313K and 1 atm
(Elsevier Science, 2015-10-01)
Rate coefficients of the reactions of Cl atoms with CF3C(O)OCH3 (k1), CF3C(O)OCH2CH3 (k2) and CF2HC(O)OCH3 (k3) have been measured for the first time in the temperature range of 287–313 K and 1 atm. Temperature dependencies ...
Conformational behaviour of methyl 2-fluoroesters through theoretical calculations, NMR and IR spectroscopy
(Royal Soc ChemistryCambridgeInglaterra, 2004)
Tropospheric degradation of 2,2,2 trifluoroethyl butyrate: Kinetic study of their reactions with OH radicals and Cl atoms at 298 K
(Elsevier Science, 2013-06)
Rate coefficients of the reactions of OH radicals and Cl atoms with 2,2,2 trifluoroethyl butyrate have been determined at 298 K and atmospheric pressure. The decay of the organics was followed using a gas chromatograph ...