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Non-carbene Complex [RuCl2(PPh3)(2)(azocane)] as Active Catalyst Precursor for ROMP and ATRP
(Springer, 2017-05-01)
The novel, non-carbene complex -[RuCl2(PPh3) (2)(azocane)] (1) of trigonal bipyramid geometry was synthesized, characterized (CHN elementary analysis, FTIR, EPR, and 31P NMR), and applied as catalyst precursor for ring ...
Ru-dimethyl sulfoxide complexes as catalysts precursors for ROMP of norbornene and ATRP of methyl methacrylate
(Elsevier B.V., 2017-02-24)
The catalytic activity of the five-coordinated [RuCl2(PPh3)(S-dmso)(2)] complex was investigated for ring opening metathesis polymerization (ROMP) of norbornene (NBE) and for atom transfer radical polymerization (ATRP) of ...
Simulation of the Equilibrium Constant Effect on the Kinetics and Average Properties of Polystyrene Obtained by ATRP
(Soc Brasileira QuimicaSao PauloBrasil, 2013)
Synthesis of poly(ethyl methacrylate-co-methyl methacrylate) obtained via ATRP using ruthenium benzylidene complexes
(Assoc Brasil Polimeros, 2018-07-01)
Atom-Transfer Radical Copolymerization (ATRP) of methyl methacrylate (MMA) and ethyl methacrylate (EMA) under different reaction conditions was conducted using Grubbs 1st (1) and 2nd (2) generation catalysts. Initially, ...
Numerical Simulation And Parametric Study Of Solution Arget Atrp Of Styrene
(Elsevier Science BVAmsterdam, 2016)
Ruthenium(II) complexes of Schiff base derived from cycloalkylamines as pre-catalysts for ROMP of norbornene and ATRP of methyl methacrylate
(2017-11-15)
Ruthenium(II) complexes of Schiff base derived from cycloalkylamines (cycloalkyl = cyclopentyl (1a), cyclohexyl (1b), cycloheptyl (1c), and cyclooctyl) (1d) were synthesized: [RuCl(CyPen-Salen)(PPh3)2] (2a), [RuCl(CyHex- ...
Atom Transfer Radical Polymerization of Methyl Methacrylate Mediated by Grubbs 1st and 2nd Generation Catalysts: Insight into the Active Species
(Soc Brasileira Quimica, 2017-01-01)
Ruthenium benzylidene complexes were evaluated as catalysts in atom-transfer radical polymerization (ATRP) of methyl methacrylate (MMA) under different reaction conditions. The mechanism by which Grubbs 1st and 2nd generation ...