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Selective one-pot synthesis of asymmetric secondary amines via N-alkylation of nitriles with alcohols
(Academic Press Inc Elsevier Science, 2019-10)
The synthesis of asymmetric secondary amines (ASA) is commonly achieved by N-alkylation of primaryamines with alcohols. Here, we investigated the ASA synthesis via the direct amination of alcohols withnitriles, which avoids ...
Phase behavior modeling of alkyl amine + hydrocarbon and alkyl amine + alcohol systems using a group contribution associating equation of state
(American Chemical Society, 2009-08)
In this work, a group contribution-associating equation of state namely GCA-EoS, is extended to model the phase behavior of alkyl amine + hydrocarbon and alkyl amine + alcohol systems while considering the association of ...
Method for the synthesis of N-alkyl-O-alkyl carbamates
(Royal Society of Chemistry, 2014-02)
Primary and secondary carbamates were prepared from primary, secondary and neo-pentyl alcohols, and carbonyl-di-imidazole (CDI), using a new three step method. Non-acidic alcohols reacted with CDI affording carbamoyl-imidazoles ...
Photoreactions of n-alkyl-3-nitrophenyl ethers with aromatic amines in SDS micelles: A laser flash photolysis study
(ELSEVIER SCIENCE SA, 2011)
The quenching of the triplet state of three n-alkyl 3-nitrophenyl ethers: 3-nitroanisol (3-NA), n-butyl 3-nitrophenyl ether (3-NB) and n-decyl 3-nitrophenyl ether (3-ND) by four aniline derivatives: aniline (AN), ...
INCLUSION COMPOUN DS OF α AND γ -CYCLODEXTRINS WITH n-ALKYL AMINE (n= 12, 18)
(Sociedad Chilena de Química, 2004)
omega-Transaminases as efficient biocatalysts to obtain novel chiral selenium-amine ligands for Pd-catalysis
(ROYAL SOC CHEMISTRY, 2010)
omega-Transaminases have been evaluated as biocatalysts in the reductive amination of organoselenium acetophenones to the corresponding amines, and in the kinetic resolution of racemic organoselenium amines. Kinetic ...
Radical amination with trimethylstannylated benzophenone imine
(American Chemical Society, 2010-04)
Intermolecular radical amination reactions of various primary, secondary, and tertiary alkyl radicals by using trimethylstannylated benzophenone imine A as a novel radical acceptor to provide imines of type B are described. ...
Self-assembly of epoxy-based polymers
(Wiley-VCH, 2009)
Amphiphilic polymers have proved to be very versatile precursors for the synthesis of nanostructured systems by self-assembly. Dendrimers, polysoaps and block copolymers have successfully been used to obtain micelles, ...