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Facilitated proton transfer-electron transfer coupled reactions at thick-film modified electrodes
(Pergamon-Elsevier Science Ltd, 2017-12)
The theory of cyclic voltammetry of facilitated proton transfer-electron transfer coupled reactions (FPT-ET reactions) in a thick organic film modified electrode is developed. It is shown that the coupling between the ...
Facilitated proton transfer via water autoprotolysis-electron transfer coupled reactions at thick-film modified electrodes
(Pergamon-Elsevier Science Ltd, 2020-07)
We present the derivation of a general mathematical model for facilitated proton transfer (FPT) reactions across a liquid|liquid (L|L) interface assisted by a protonatable neutral weak base at a thick organic film modified ...
Facilitated proton transfer reactions via water autoprotolysis across oil|water interfaces. Half-wave potential
(Pergamon-Elsevier Science Ltd, 2020-02)
The main purpose of this paper is to develop the equations for the half-wave potentials of facilitated proton transfer or protonated species transfer across liquid|liquid interfaces, explicitly considering the water ...
Effect of ligand protonation on the facilitated ion transfer reactions across oil|water interfaces. V. Applications of forced hydrodynamic conditions
(Elsevier Science Sa, 2016-03-05)
Hydrodynamic forced conditions applied to the aqueous or the organic phase during a potential sweep can be used to elucidate themechanisms of ion transfer across liquid|liquid interfaces. The aimof this study is to confirm ...
Facilitated proton transfer reactions via water autoprotolysis across oil|water interfaces. Spectroelectrochemical analysis
(Pergamon-Elsevier Science Ltd, 2019-03)
In this paper, we present an integrated experimental-theoretical approach to evaluate the spectroelectrochemical response of the facilitated proton transfer processes via water autoprotolysis at the liquid|liquid (L|L) ...
An integrated theoretical-experimental approach to understand facilitated proton transfer-electron transfer coupled reactions at thick-film modified electrodes
(Pergamon-Elsevier Science Ltd, 2018-09)
The main purpose of the current work is to generalize the analytical model for the facilitated proton transfer-electron transfer coupled reactions at thick organic film-modified electrodes, including ion pairing in the ...
Facilitated proton transfer across liquid | liquid interfaces under forced hydrodynamic conditions. Determination of partition coefficients of neutral weak bases
(Elsevier Science Sa, 2017-04)
A novel quantitative methodology to determine the partition coefficients of neutral weak bases is developed. This new electrochemical approach is based on the measurement of the total transferred charge across the oil | water ...
Understanding the Physics and Chemistry of Reaction Mechanisms from Atomic Contributions: A Reaction Force Perspective
(AMER CHEMICAL SOC, 2012)
Studying chemical reactions involves the knowledge of the reaction mechanism. Despite activation barriers describing the kinetics or reaction energies reflecting thermodynamic aspects, identifying the underlying physics ...
Intense White Molecular Fluorescence from Naphthoxazole-Quinoline Derivatives
(Blackwell Publishing Inc., 2018)
© 2018 The American Society of Photobiology Naphthoxazole derivatives are small heterocyclic compounds endowed with outstanding fluorescence properties. In this work, we report a detailed study of the intense white light ...
Ambient Solid-state Mechano-chemical Reactions Between Functionalized Carbon Nanotubes
(NATURE PUBLISHING GROUPLONDON, 2015)