Artículos de revistas
Mono- and dinuclear palladium(II) compounds containing N,S donor ligands - Synthesis, characterization and thermal behavior
Fecha
2007-03-01Registro en:
Journal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 87, n. 3, p. 721-724, 2007.
1388-6150
10.1007/s10973-006-7770-4
WOS:000244823700021
Autor
Universidade Estadual Paulista (Unesp)
Institución
Resumen
Synthesis, spectroscopic characterization and thermal analysis of the compounds [Pd-2(dmba)(2)(mu-NCO)(mu-2-qnS)] (1), [Pd-2(dmba)(2)(mu-NCO)(mu-8-qnS)] (2), [Pd(2-qnS)(2)] (3) and [Pd(8-qn(S))2] (4) (dmba=N,N-dimethylbenzylamine; 2-qnS=2-quinolinethiolate; 8-qnS=8-quinolinethiolate) are described. The thermal decomposition of these compounds occurs in four consecutive steps and the final decomposition products were identified as Pd(0) by X-ray powder diffraction. The thermal stability order of the complexes is 4 > 3 > 1 > 2.