Actas de congresos
Thermochemical Parameters Of α-picoline N-oxide Adducts Of Some Divalent Transition Metal Bromides
Registro en:
Journal Of Thermal Analysis And Calorimetry. , v. 79, n. 2, p. 355 - 359, 2005.
13886150
2-s2.0-18244390710
Autor
Dunstan P.O.
Institución
Resumen
Thermochemical parameters for the adducts [MBr2(α-picoNO) n] (where M is Mn(II), Fe(II), Co(II), Ni(II), Cu(II) or Zn(II); α-picoNO is α-picoline N-oxide and n=2 or 4) were determined through reaction-solution calorimetry in methanol or aqueous 1.2 M HCl at 298 K as the standard enthalpies for the Lewis acid/base reactions, the standard enthalpies of formation, the lattice standard enthalpies, the standard enthalpies of decomposition and the standard enthalpies for the Lewis acid/base reactions in the gaseous phase. The mean bond dissociation standard enthalpies of the M(II)-oxygen coordinated bond were calculated by using the standard molar enthalpies of formation of the gaseous adducts. ©2005Akadé miaiKiadó,Budapest. 79 2 355 359 Schmauss, V.G., Specker, H., (1968) Z. Anorg. Allg. Chem., 363, p. 113 Brown, D.H., Kenyon, D., Sharp, D.W.A., (1964) J. Chem. Soc. (A), p. 1474 Karayannis, N.M., Pytelewski, L.L., Mikulski, C., (1973) Coord. Chem. Rev., 11, p. 93 Radhoff, G., Ohrbach, K.H., Kettrup, A., (1985) Thermochim. Acta, 85, p. 71 West, D.X., Severns, J.C., (1988) Transition Met. Chem., 13, p. 45 Guagliano, J.V., Fujita, J., Franz, G., Phillips, D.J., Walmsley, J.A., Tyree, S.Y., (1961) J. Am. Chem. Soc., 83, p. 3770 Carlin, R.L., (1961) J. Am. Chem. Soc., 83, p. 3773 West, D.X., Goodman, L.K., (1985) Inorg. Chim. Acta, 104, p. 161 West, D.X., Nipp, C.A., (1986) Lnorg. Chim. Acta, 118, p. 157 West, D.X., Nipp, C.A., (1987) Inorg. Chim. Acta, 127, p. 129 West, D.X., Nipp, C.A., (1985) Transition Met. Chem., 10, p. 201 West, D.X., Sevems, J.C., (1986) Transition Met. Chem., 11, p. 151 Dunstan, P.O., (2003) Thermochim. Acta, 409, p. 19 Boekelheide, V., Linn, W.J., (1954) J. Am. Chem. Soc., 46, p. 1286 Flaschka, H.A., (1964) EDTA Titrations: An Introduction to Theory and Practice, pp. 80-82. , Pergamon Press, 2nd Ed., London Koltoff, I.M., Sandall, E.B., (1956) Tratado de Química Analítica Cuantitativa, Libreria y Editorial Nigra S. R. L., 3a Ed., p. 371. , Buenos Aires Botelho, J.R., Gondim, A.D., Santos, I.M.G., Dunstan, P.O., Souza, A.G., Fernandes Jr., V.J., Araújo, A.S., (2004) J. Therm. Anal. Cal., 75, p. 607 Kida, S., Quagliano, J.V., Walmsley, J.A., Tyree, S., (1963) Spectrochim. Acta, 19, p. 189 Katritzky, A.R., Hands, A.R., (1958) J. Chem. Soc. (London), 11, p. 2195 Wiley, R.H., Slaymaker, S.C., (1957) J. Am. Chem. Soc., 79, p. 2233 Shindo, H., (1956) Pharm. Bull. (Tokyo), 4, p. 460 Dunstan, P.O., (2004) Thermochim. Acta, 419, p. 89 Lever, A.B.P., (1968) J. Chem. Educ., 45, p. 711 Bolster, M.W., (1972) The Coordination Chemistry of Aminophosphine Oxides and Related Compounds, p. 88. , Thesis, Leiden Reedijk, K., Van Leeuwen, P.W.N.M., Groeneveld, W.L., (1968) Recueil Trans. Chim., 87, p. 129 Wagmam, D.D., Evans, W.H., Parker, V.B., Schumn, R.H., Halow, I., Churney, S., Nuttall, R.L., (1982) J. Phys. Chem. Ref. Data, V(II), pp. 2-50 Dunstan, P.O., (1991) Thermochim. Acta, 181, p. 143 Skinner, H., Pilcher, G., (1973) Q. Rev. Chem. Soc., 17, p. 264